4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

Base Information

Chemical Name:4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde
CAS No.:1026985-18-1
Molecular Formula:C₂₉H₃₆O₄Si
Molecular Weight:476.688
Hs Code.:

4-(<i>tert</i>-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

Synonyms:4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

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Chemical Property of 4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

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Technology Process of 4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

There total 6 articles about 4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 864545-38-0
4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butan-1-ol

: 1026985-18-1
4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -70 - 20 ℃; for 1h;
DOI:10.1021/ol051175m

Reference yield:

: 105-13-5
4-Methoxybenzyl alcohol

: 1026985-18-1
4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: Et₃B / Pd₂(dba)3; (S,S)-1,2-bis(2-diphenylphosphanyl-benzoylamino)cyclohexane / CH₂Cl₂ / 6 h / 20 °C

2.1: BH₃*THF / tetrahydrofuran / 13 h / 0 - 20 °C

2.2: NaOH; H₂O₂ / tetrahydrofuran; H₂O / 8 h / 20 - 50 °C

3.1: imidazole; DMAP / CH₂Cl₂

4.1: oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / 1 h / -70 - 20 °C

With 1H-imidazole; dmap; borane-THF; oxalyl dichloride; triethyl borane; dimethyl sulfoxide; triethylamine; trans-1,2-(1S,2S)-1,2-diaminocyclohexane-N,N’-bis(2’-diphenylphosphinobenzoyl); tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol051175m

Reference yield:

: 1838-94-4
isoprene epoxide

: 1026985-18-1
4-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-2-methyl-butyraldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: Et₃B / Pd₂(dba)3; (S,S)-1,2-bis(2-diphenylphosphanyl-benzoylamino)cyclohexane / CH₂Cl₂ / 6 h / 20 °C

2.1: BH₃*THF / tetrahydrofuran / 13 h / 0 - 20 °C

2.2: NaOH; H₂O₂ / tetrahydrofuran; H₂O / 8 h / 20 - 50 °C

3.1: imidazole; DMAP / CH₂Cl₂

4.1: oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / 1 h / -70 - 20 °C

With 1H-imidazole; dmap; borane-THF; oxalyl dichloride; triethyl borane; dimethyl sulfoxide; triethylamine; trans-1,2-(1S,2S)-1,2-diaminocyclohexane-N,N’-bis(2’-diphenylphosphinobenzoyl); tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol051175m