Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid

Base Information

• Chemical Name: Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid
• CAS No.: 75810-02-5
• Molecular Formula: C₂₃H₃₀BrIO₉
• Molecular Weight: 657.294
• Mol file: 75810-02-5.mol

Synonyms:Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid

Chemical Property of Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid

There total 3 articles about Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4,6-O-benzyliden-2-desoxy-α-D-arabino-hexopyranosid (70717-91-8,78086-68-7) → Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid (75810-02-5)

Guidance literature:

With N-Bromosuccinimide; barium carbonate; In tetrachloromethane; for 0.25h; Heating;

Reference yield:

4-O-Acetyl-1,5-anhydro-2,6-didesoxy-3-C-methyl-D-arabino-hex-1-enit (78086-64-3) → Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid (75810-02-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 62 percent / N-iodosuccinimide / acetonitrile / 5 °C

2: 63 percent / N-bromosuccinimide, BaCO₃ / CCl₄ / 0.25 h / Heating

With N-Bromosuccinimide; N-iodo-succinimide; barium carbonate; In tetrachloromethane; acetonitrile;

Reference yield:

methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside (6752-48-3,16718-95-9,18424-62-9,19877-02-2,22886-97-1,52153-29-4,52612-68-7,55331-65-2,64978-95-6,65725-24-8,66512-93-4,67968-51-8,72904-80-4,77481-69-7,131615-73-1,138663-49-7,151214-39-0) → Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid (75810-02-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 62 percent / N-iodosuccinimide / acetonitrile / 5 °C

2: 63 percent / N-bromosuccinimide, BaCO₃ / CCl₄ / 0.25 h / Heating

With N-Bromosuccinimide; N-iodo-succinimide; barium carbonate; In tetrachloromethane; acetonitrile;

upstream raw materials:

Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4,6-O-benzyliden-2-desoxy-α-D-arabino-hexopyranosid

4-O-Acetyl-1,5-anhydro-2,6-didesoxy-3-C-methyl-D-arabino-hex-1-enit

methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside

Downstream raw materials:

Methyl-3-O-(4-O-acetyl-2,6-didesoxy-3-C-methyl-α-D-arabinohexopyranosyl)-4-O-benzoyl-2,6-didesoxy-α-D-arabino-hexopyranosid