trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

Base Information

Chemical Name:trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]
CAS No.:488780-58-1
Molecular Formula:C₄₂H₄₇ClN₂P₂Ru
Molecular Weight:778.319
Hs Code.:

trans-[Ru(H)(Cl)(P(C<sub>6</sub>H<sub>5</sub>)3)2(2,3-diamino-2,3-dimethylbutane)]

Synonyms:trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

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Chemical Property of trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

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Technology Process of trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

There total 2 articles about trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 55102-19-7
hydridochlorotris(triphenylphosphine)ruthenium(II)

: 20485-44-3
2,3-dimethyl-2,3-diaminobutane

: 488780-58-1
trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

: cis-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

Guidance literature:: In tetrahydrofuran; under N2 atm. using Schlenk techniques; (H2NCMe2)2 stirred into suspn. of RuHCl(PPh3)3 in THF for 20 min; black ppt. filtered; to filtrate hexane added; solid filtered; washed (hexane/THF, and hexane); dried (vac.); concd. soln. in THF layered (hexane); elem. anal.;

Reference yield:

: [Ru(H)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane(-H))]

: 847481-90-7
OsHCl(2,3-diamino-2,3-dimethylbutane)(triphenylphosphine)2

: 488780-58-1
trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

: OsHCl(NHCMe₂CMe₂NH₂)(triphenylphosphine)2

Guidance literature:: In benzene-d6; addn. of excess of osmium complex to ruthenium complex in NMR tube, dissolving in benzene-d6, keeping for 24 h; detected by NMR;
DOI:10.1021/om048998k

Reference yield: 94.0%

: 488780-58-1
trans-[Ru(H)(Cl)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane)]

: [Ru(H)(P(C₆H₅)3)2(2,3-diamino-2,3-dimethylbutane(-H))]

Guidance literature:: With potassium tert-butoxide; In tetrahydrofuran; byproducts: HCl; under Ar atm. using Schlenk techniques; KOBu added slowly to soln. of Ru-complex in THF; soln. stirred for 2 h; soln. filtered; washed; filtrate evapd. to dryness; residue stirred (hexane); filtered; washed (Et2O); dried (vac.);