(-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

Base Information

Chemical Name:(-)-(S_P)-Cyclohexylmethylphenylphosphine oxide
CAS No.:37775-94-3
Molecular Formula:C₁₃H₁₉OP
Molecular Weight:222.267
Hs Code.:

(-)-(S<sub>P</sub>)-Cyclohexylmethylphenylphosphine oxide

Synonyms:(-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

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Chemical Property of (-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

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Technology Process of (-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

There total 14 articles about (-)-(S_P)-Cyclohexylmethylphenylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: cyclohexenylmethylphenylphosphine oxide

: 37775-94-3
(-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

Guidance literature:: With hydrogen; Lindlar's catalyst; In methanol; for 6h; Ambient temperature;
DOI:10.1021/jo00183a009

Reference yield: 55.0%

: 108-85-0
1-bromocyclohexane

: 7301-81-7,34638-79-4,33642-98-7
ethyl (S)-methyl(phenyl)phosphinate

: 37775-94-3
(-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

Guidance literature:: 1-bromocyclohexane; With iodine; magnesium; In tetrahydrofuran; Schlenk technique; Inert atmosphere; Heating;

ethyl (S)-methyl(phenyl)phosphinate; In tetrahydrofuran; at 20 ℃; for 12h; enantioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1039/d1cc00646k

Reference yield:

: 77085-89-3
(-)-(S_P)-<(menthoxycarbonyl)methyl>phenylvinylphosphine oxide

: 37775-94-3
(-)-(S_P)-Cyclohexylmethylphenylphosphine oxide

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / water, LiCl / dimethylsulfoxide / 2 h / Heating

2: 78 percent / toluene / 24 h / 180 °C

3: 92 percent / H₂ / Pd/CaCO₃ / methanol / 6 h / Ambient temperature

With water; hydrogen; lithium chloride; Lindlar's catalyst; In methanol; dimethyl sulfoxide; toluene;
DOI:10.1021/jo00183a009