(2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

Base Information

Chemical Name:(2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester
CAS No.:1452798-24-1
Molecular Formula:C₁₃H₁₇NO₄Se
Molecular Weight:330.242
Hs Code.:

Synonyms:(2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

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Chemical Property of (2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

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Technology Process of (2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

There total 2 articles about (2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1666-13-3
diphenyl diselenide

: 1452798-23-0
(2S)-2-carboxymethylamino-4-bromo-butyric acid methyl ester

: 1452798-24-1
(2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

Guidance literature:: diphenyl diselenide; With sodium tetrahydroborate; In methanol; Inert atmosphere;

(2S)-2-carboxymethylamino-4-bromo-butyric acid methyl ester; In methanol; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1002/chem.201204209

Reference yield:

: 177325-78-9
(2S)-2-amino-4-bromo-butyric acid methyl ester hydrobromide

: 1452798-24-1
(2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydrogencarbonate / 1,4-dioxane; water / 16 h / 0 °C / Inert atmosphere

2.1: sodium tetrahydroborate / methanol / Inert atmosphere

2.2: 2 h / 20 °C / Inert atmosphere

With sodium tetrahydroborate; sodium hydrogencarbonate; In 1,4-dioxane; methanol; water;
DOI:10.1002/chem.201204209

Reference yield:

: 1452798-24-1
(2S)-2-methyloxycarbonylamino-4-phenylselenylbutyric acid methyl ester

: 1452798-34-3
(αS,βS)-α-[(methoxycarbonyl)amino]-β-(trimethylsilyloxy)-4,6-dimethyl-9-oxo-3-(2',3',5'-tri-O-acetyl-β-D-ribofuranosyl)-4,9-dihydro-3H-imidazo[1,2-α]purine-7-butanoic acid methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: pyridine; dihydrogen peroxide / tetrahydrofuran / 1.5 h / Reflux

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 96 h / 20 °C / Inert atmosphere

3.1: magnesium iodide / diethyl ether; toluene / 1.5 h / -50 °C / Inert atmosphere

4.1: pyridine / dichloromethane / 43 h / 20 °C / Inert atmosphere

5.1: 2-methylpropylmagnesium chloride / tetrahydrofuran / 0.5 h / -78 °C / Schlenk technique; Inert atmosphere

5.2: 16 h / -78 - -25 °C / Schlenk technique; Inert atmosphere

With pyridine; 2-methylpropylmagnesium chloride; dihydrogen peroxide; 3-chloro-benzenecarboperoxoic acid; magnesium iodide; In tetrahydrofuran; diethyl ether; dichloromethane; toluene;
DOI:10.1002/chem.201204209