(3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

Base Information

Chemical Name:(3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate
CAS No.:1310340-05-6
Molecular Formula:C₁₁H₁₅F₃O₃S
Molecular Weight:284.3
Hs Code.:

Synonyms:(3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

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Technology Process of (3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

There total 1 articles about (3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: (2R,5S)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-one

: 1310340-05-6
(3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

Guidance literature:: (2R,5S)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-one; With n-butyllithium; diisopropylamine; In tetrahydrofuran; at -78 ℃; for 2h; Inert atmosphere;

N,N-phenylbistrifluoromethane-sulfonimide; In tetrahydrofuran; Inert atmosphere;
DOI:10.1016/j.bmc.2011.03.033

Reference yield: 76.0%

: 1310340-05-6
(3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

: ethyl (2E,4E,6Z,8E)-3,7-dimethyl-9-(tri-n-butylstannyl)-nona-2,4,6,8-tetraenoate

: 1310340-12-5
ethyl (2E,4E,6Z,8E)-3,7-dimethyl-9-((3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl)-2,4,6,8-nonatetraenoate

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenyl-arsane; cesium fluoride; In N,N-dimethyl-formamide; at 45 ℃; Inert atmosphere;
DOI:10.1016/j.bmc.2011.03.033

Reference yield:

: 1310340-05-6
(3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl trifluoromethanesulfonate

: 1310340-21-6
(2E,4E,6Z,8E)-3,7-dimethyl-9-((3S,6R)-3-methyl-6-(1-propen-2-yl)-1-cyclohexen-1-yl)-2,4,6,8-nonatetraenoic acid

Guidance literature:: Multi-step reaction with 2 steps

1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenyl-arsane; cesium fluoride / N,N-dimethyl-formamide / 45 °C / Inert atmosphere

2: potassium hydroxide / ethanol; water / 50 °C

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenyl-arsane; cesium fluoride; potassium hydroxide; In ethanol; water; N,N-dimethyl-formamide; 1: Stille coupling;
DOI:10.1016/j.bmc.2011.03.033