2,5-dimethylphenyl nonaflate

Base Information

• Chemical Name: 2,5-dimethylphenyl nonaflate
• CAS No.: 252573-81-2
• Molecular Formula: C₁₂H₉F₉O₃S
• Molecular Weight: 404.253
• Mol file: 252573-81-2.mol

Synonyms:2,5-dimethylphenyl nonaflate

Chemical Property of 2,5-dimethylphenyl nonaflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2,5-dimethylphenyl nonaflate

There total 2 articles about 2,5-dimethylphenyl nonaflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2.6-dimethylphenol (576-26-1,25134-01-4) + para-nitrophenyl perfluorobutanesulfonate (32848-23-0) → 2,5-dimethylphenyl nonaflate (252573-81-2)

Guidance literature:

With 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene on polystyrene.HL; In acetonitrile; at 80 ℃;

DOI:10.1016/S0040-4039(99)01529-4

Reference yield: 58.0%

2.6-dimethylphenol (576-26-1,25134-01-4) + Nonafluorobutanesulfonyl fluoride (375-72-4) → 2,5-dimethylphenyl nonaflate (252573-81-2)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1021/jo034962a

Reference yield: 97.0%

Benzophenone imine (1013-88-3) + 2,5-dimethylphenyl nonaflate (252573-81-2) → N-(2,6-dimethylphenyl)-1,1-diphenylmethanimine (119971-04-9)

Guidance literature:

With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In toluene; at 105 ℃; for 24h;

DOI:10.1021/jo034962a

upstream raw materials:

2.6-dimethylphenol

para-nitrophenyl perfluorobutanesulfonate

Nonafluorobutanesulfonyl fluoride

Downstream raw materials:

4-(2,6-dimethylphenyl)morpholine

N-(2,6-dimethylphenyl)-1,1-diphenylmethanimine