phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

Base Information

Chemical Name:phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside
CAS No.:1257634-63-1
Molecular Formula:C₃₂H₄₀O₅SSi
Molecular Weight:564.818
Hs Code.:

Synonyms:phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

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Chemical Property of phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

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Technology Process of phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

There total 1 articles about phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 158716-08-6
phenyl 4,6-O-benzylidene-2-O-benzyl-1-deoxy-1-thio-α-D-mannopyranoside

: 1257634-63-1
phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 14h;
DOI:10.1021/jo101453y

Reference yield: 81.0%

: 13735-81-4
1-styrenyloxytrimethylsilane

: 1257634-63-1
phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

: 1257634-76-6
4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-(2-oxo-2-phenylethyl)-β-D-mannopyranose

Guidance literature:: phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside; With trifluoromethylsulfonic anhydride; 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -55 ℃; for 0.5h; Inert atmosphere; Molecular sieve;

1-styrenyloxytrimethylsilane; In dichloromethane; at -55 ℃; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1021/jo101453y

Reference yield: 76.0%

: 1257634-63-1
phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside

: 24850-33-7
allyltributylstanane

: 1257634-75-5
4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-allyl-β-D-mannopyranose

Guidance literature:: phenyl 4,6-O-benzylidene-2-O-benzyl-3-O-tert-butyldimethylsilyl-1-deoxy-1-thio-α-D-mannopyranoside; With trifluoromethylsulfonic anhydride; 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -55 ℃; for 0.5h; Inert atmosphere; Molecular sieve;

allyltributylstanane; In dichloromethane; at -55 ℃; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1021/jo101453y