[5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc

Base Information

• Chemical Name: [5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc
• CAS No.: 1200931-10-7
• Molecular Formula: C₁₀₂H₁₅₄N₄O₄SiZn
• Molecular Weight: 1593.84
• Mol file: 1200931-10-7.mol

Synonyms:[5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc

Chemical Property of [5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc

There total 1 articles about [5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

trihexylsilyl chloride (3634-67-1) + [5,15-bis(ethynyl)-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc (1200931-08-3) → [5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc (1200931-10-7)

Guidance literature:

[5,15-bis(ethynyl)-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

trihexylsilyl chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 6.25h; Inert atmosphere;

DOI:10.1021/la9031927

Reference yield: 60.0%

4-iodobenzoic acid (619-58-9) + [5-ethynyl-15-(trihexylsilanyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc (1200931-10-7) → C109H158N4O6SiZn (1200931-12-9)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; triethylamine; triphenylphosphine; In toluene; at 20 ℃; for 12.1667h; Inert atmosphere;

DOI:10.1021/la9031927

upstream raw materials:

trihexylsilyl chloride

[5,15-bis(ethynyl)-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato]zinc

Downstream raw materials:

C₁₀₉H₁₅₈N₄O₆SiZn