(Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate

Base Information

• Chemical Name: (Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate
• CAS No.: 1602573-41-0
• Molecular Formula: C₁₄H₁₆O₄
• Molecular Weight: 248.279
• Mol file: 1602573-41-0.mol

Synonyms:(Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate

Chemical Property of (Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate

There total 1 articles about (Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1-isopropyl-3-phenylprop-2-yn-1-yl methyl carbonate (505087-61-6) → (Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate (1602573-41-0)

Guidance literature:

With silver hexafluoroantimonate; 3,5-dicholoropyridine N-oxide; [1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2-(3H)-ylidene]gold(I)chloride; In 1,2-dichloro-ethane; at 20 ℃; for 1.5h; stereoselective reaction; Schlenk technique; Glovebox; Inert atmosphere;

DOI:10.1021/jo500573s

Reference yield: 59.0%

(Z)-methyl (4-methyl-1-oxo-1-phenylpent-2-en-2-yl)carbonate (1602573-41-0) → 5-hydroxy-2-isopropyl-3-methyl-5-phenylcyclopent-2-enone (1602573-54-5)

Guidance literature:

With sodium hydroxide; In acetone; at 20 ℃; regioselective reaction;

DOI:10.1021/jo500573s

upstream raw materials:

1-isopropyl-3-phenylprop-2-yn-1-yl methyl carbonate

Downstream raw materials:

5-hydroxy-2-isopropyl-3-methyl-5-phenylcyclopent-2-enone