N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

Base Information

Chemical Name:N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide
CAS No.:1235871-74-5
Molecular Formula:C₃₃H₂₆BrNO₅
Molecular Weight:596.477
Hs Code.:

Synonyms:N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

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Chemical Property of N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

Chemical Property:

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Technology Process of N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

There total 14 articles about N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1235871-73-4
N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromobenzo[1,3]dioxole-4-carboxamide

: 74-88-4
methyl iodide

: 1235871-74-5
N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1016/j.bmcl.2012.09.097

Reference yield:

: 52401-42-0
1-amino-6,7-dimethoxynaphthalene

: 1235871-74-5
N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

Guidance literature:: Multi-step reaction with 4 steps

1: iodine; pyridine / 1,4-dioxane / 0 - 20 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; toluene / 90 °C

3: triethylamine / dichloromethane / 20 °C

4: sodium hydride / N,N-dimethyl-formamide / 20 °C

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; iodine; sodium hydride; sodium carbonate; triethylamine; In 1,4-dioxane; dichloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.bmcl.2012.09.097

Reference yield:

: 7311-22-0
2,3-dimethoxy-5-nitronaphthalene

: 1235871-74-5
N-(4-(biphenyl-4-yl)-6,7-dimethoxynaphthalen-1-yl)-5-bromo-N-methylbenzo[1,3]dioxole-4-carboxamide

Guidance literature:: Multi-step reaction with 5 steps

1: palladium 10% on activated carbon; hydrazine hydrate / ethanol / 85 °C

2: iodine; pyridine / 1,4-dioxane / 0 - 20 °C

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; toluene / 90 °C

4: triethylamine / dichloromethane / 20 °C

5: sodium hydride / N,N-dimethyl-formamide / 20 °C

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; palladium 10% on activated carbon; iodine; sodium hydride; sodium carbonate; hydrazine hydrate; triethylamine; In 1,4-dioxane; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.bmcl.2012.09.097