O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate

Base Information

• Chemical Name: O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate
• CAS No.: 133129-84-7
• Molecular Formula: C₂₁H₂₈OS₂
• Molecular Weight: 360.585
• Mol file: 133129-84-7.mol

Synonyms:O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate

Chemical Property of O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate

There total 4 articles about O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-ethyl 4-phenylpent-2-enoate (115476-97-6) → O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate (133129-84-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 1) LDA, HMPA / 1) THF, -78 deg C, 15 min, 2) THF, 20 min

2: 1) LDA, HMPA / 1) THF, -78 deg C, 15 min, 2) THF, 20 min

3: LiAlH₄ / diethyl ether

4: 1) NaH / 1) THF, room temp., 1.5 h, 2) 2 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; sodium hydride; lithium diisopropyl amide; In diethyl ether;

DOI:10.1021/jo00008a048

Reference yield:

(E)-2-((Z)-2-Phenyl-propenyl)-hex-4-enoic acid ethyl ester → O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate (133129-84-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 1) LDA, HMPA / 1) THF, -78 deg C, 15 min, 2) THF, 20 min

2: LiAlH₄ / diethyl ether

3: 1) NaH / 1) THF, room temp., 1.5 h, 2) 2 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; sodium hydride; lithium diisopropyl amide; In diethyl ether;

DOI:10.1021/jo00008a048

Reference yield:

(E)-2-((E)-But-2-enyl)-2-((Z)-2-phenyl-propenyl)-hex-4-enoic acid ethyl ester (133129-99-4) → O-2-(2-phenyl-1(Z)-propenyl)-2-(2(E)-butenyl)-4(Z)-hexenyl S-methyl dithiocarbonate (133129-84-7)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether

2: 1) NaH / 1) THF, room temp., 1.5 h, 2) 2 h

With lithium aluminium tetrahydride; sodium hydride; In diethyl ether;

DOI:10.1021/jo00008a048

upstream raw materials:

carbon disulfide

(E)-2-((E)-But-2-enyl)-2-((Z)-2-phenyl-propenyl)-hex-4-en-1-ol

methyl iodide

(E)-ethyl 4-phenylpent-2-enoate