diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate

Base Information

• Chemical Name: diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate
• CAS No.: 122570-95-0
• Molecular Formula: C₂₄H₃₀NO₃P
• Molecular Weight: 411.481
• Mol file: 122570-95-0.mol

Synonyms:diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate

Chemical Property of diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate

There total 7 articles about diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diethyl N-(diphenylmethylene) aminomethyl phosphonate (122570-91-6) + 2,5-Dichloro-benzoic acid cyclohex-2-enyl ester → diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate (122570-95-0)

Guidance literature:

bis[1,2-bis(diphenylphosphino)ethane]palladium⁽⁰⁾; In 1,2-dimethoxyethane; at 20 ℃; for 5h;

DOI:10.1016/S0040-4039(00)80546-8

Reference yield: 67.0%

rac-3-acetoxycyclohexene (76644-52-5,76704-31-9,14447-34-8,62247-41-0) + diethyl N-(diphenylmethylene) aminomethyl phosphonate (122570-91-6) → diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate (122570-95-0)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); potassium hydride; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; for 16h;

DOI:10.1016/0957-4166(95)00059-X

Reference yield: 5.0%

diethyl N-(diphenylmethylene) aminomethyl phosphonate (122570-91-6) + Phenyl acetate (122-79-2,34474-31-2) → diethyl <(benzhydrylideneamino cyclohex-2-enyl)methyl>phosphonate (122570-95-0)

Guidance literature:

bis[1,2-bis(diphenylphosphino)ethane]palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 40h;

DOI:10.1016/S0040-4039(00)80546-8

upstream raw materials:

rac-3-acetoxycyclohexene

diethyl N-(diphenylmethylene) aminomethyl phosphonate

1-(ethoxycarbonyloxy)-2-cyclohexene

2,4-Dichloro-benzoic acid cyclohex-2-enyl ester

Downstream raw materials:

diethyl <(amino cyclohex-2-enyl)methyl>phosphonate