C₇₅H₁₀₆O₁₁Si₂

Base Information

Chemical Name:C₇₅H₁₀₆O₁₁Si₂
CAS No.:931113-76-7
Molecular Formula:C₇₅H₁₀₆O₁₁Si₂
Molecular Weight:1239.83
Hs Code.:

C<sub>75</sub>H<sub>106</sub>O<sub>11</sub>Si<sub>2</sub>

Synonyms:C₇₅H₁₀₆O₁₁Si₂

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Chemical Property of C₇₅H₁₀₆O₁₁Si₂

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Technology Process of C₇₅H₁₀₆O₁₁Si₂

There total 27 articles about C₇₅H₁₀₆O₁₁Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: 931113-68-7
C₃₉H₆₀O₆Si₂

: C₅₄H₆₂O₆P⁽¹⁺⁾*I^(1-)

: 931113-76-7
C₇₅H₁₀₆O₁₁Si₂

Guidance literature:: C₅₄H₆₂O₆P⁽¹⁺⁾*I^(1-); With potassium hexamethylsilazane; In toluene; at -78 ℃; for 0.5h;

C₃₉H₆₀O₆Si₂; In toluene; at -78 - 20 ℃; Further stages.;
DOI:10.1021/jo062513f

Reference yield:

: 871840-51-6
tert-butyldimethyl((4-methylpent-4-en-1-yl)oxy)silane

: 931113-76-7
C₇₅H₁₀₆O₁₁Si₂

Guidance literature:: Multi-step reaction with 21 steps

1.1: 36.0 g / (DHQ)2PHAL; K₃[Fe(CN)6]; K₂CO₃ / K₂OsO₂(OH)4 / 2-methyl-propan-2-ol; H₂O / 48 h / 0 °C

2.1: PPTS / CH₂Cl₂ / 1.5 h / 20 °C

3.1: 21.77 g / TBAF / tetrahydrofuran / 2 h / cooling

4.1: 59 percent / Ph₃P; DIAD / tetrahydrofuran / 24 h / 20 °C

5.1: 60 percent / MCPBA / CH₂Cl₂ / 16 h / 20 °C

6.1: 84 percent / KHMDS / 1,2-dimethoxy-ethane; toluene / 2.5 h / -78 - 20 °C

7.1: 90 percent / DIBAL-H / CH₂Cl₂ / 1.5 h / -78 °C

8.1: 96 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂; H₂O / 3 h / 20 °C

9.1: KHMDS / tetrahydrofuran / 0.5 h / -78 °C

9.2: 99 percent / tetrahydrofuran / 1 h / -78 °C

10.1: Hg(OAc)2 / tetrahydrofuran; H₂O / 1 h / cooling

10.2: 72 percent / NaBH₄ / tetrahydrofuran; H₂O / 2 h

11.1: 99 percent / imidazole; DMAP / dimethylformamide / 0.5 h

12.1: 37 percent / PPTS / methanol / 3 h / Heating

13.1: Et₃N; MsCl / CH₂Cl₂ / 0.83 h / 0 °C

13.2: 81 percent / DBU / CH₂Cl₂ / 4 h / 20 °C

14.1: (DHQD)2PHAL; K₃[Fe(CN)6]; K₂CO₃ / potassium osmate dihydrate; K₂S₂O₈ / 2-methyl-propan-2-ol; H₂O / 16 h / cooling

15.1: 91 percent / PPTS / methanol; CH₂Cl₂ / 2.08 h / -78 - 20 °C

16.1: 59 percent / KHMDS / tetrahydrofuran; toluene / 16 h / cooling

17.1: 83 percent / KH / tetrahydrofuran; various solvent(s) / 2 h

18.1: 99 percent / TBAF / tetrahydrofuran / 16 h / 20 °C

19.1: 67 percent / Ph₃P; iodine; imidazole / benzene / 1 h / 20 °C

20.1: 70 percent / i-Pr₂NEt / acetonitrile / 48 h / 90 °C

21.1: KHMDS / toluene / 0.5 h / -78 °C

21.2: 26 percent / toluene / -78 - 20 °C

With pyridine; 1H-imidazole; dmap; Hydroquinone 1,4-phthalazinediyl diether; di-isopropyl azodicarboxylate; mercury(II) diacetate; tetrabutyl ammonium fluoride; iodine; pyridinium p-toluenesulfonate; potassium hydride; potassium hexamethylsilazane; diisobutylaluminium hydride; potassium carbonate; Dess-Martin periodane; methanesulfonyl chloride; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; potassium hexacyanoferrate(III); potassium osmate(VI); dipotassium peroxodisulfate; potassium dioxotetrahydroxoosmate(VI); In tetrahydrofuran; methanol; 1,2-dimethoxyethane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; tert-butyl alcohol; benzene; 4.1: Mitsunobu reaction / 6.1: Julia-Kocienski coupling / 8.1: Dess-Martin oxidation / 9.2: Wittig olefination / 21.2: Wittig olefination;
DOI:10.1021/jo062513f

Reference yield:

: 931113-55-2
(S)-5-(3-(2-(4-methoxyphenyl)-4-methyl-1,3-dioxolan-4-yl)propylsulfonyl)-1-phenyl-1H-tetrazole

: 931113-76-7
C₇₅H₁₀₆O₁₁Si₂

Guidance literature:: Multi-step reaction with 16 steps

1.1: 84 percent / KHMDS / 1,2-dimethoxy-ethane; toluene / 2.5 h / -78 - 20 °C

2.1: 90 percent / DIBAL-H / CH₂Cl₂ / 1.5 h / -78 °C

3.1: 96 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂; H₂O / 3 h / 20 °C

4.1: KHMDS / tetrahydrofuran / 0.5 h / -78 °C

4.2: 99 percent / tetrahydrofuran / 1 h / -78 °C

5.1: Hg(OAc)2 / tetrahydrofuran; H₂O / 1 h / cooling

5.2: 72 percent / NaBH₄ / tetrahydrofuran; H₂O / 2 h

6.1: 99 percent / imidazole; DMAP / dimethylformamide / 0.5 h

7.1: 37 percent / PPTS / methanol / 3 h / Heating

8.1: Et₃N; MsCl / CH₂Cl₂ / 0.83 h / 0 °C

8.2: 81 percent / DBU / CH₂Cl₂ / 4 h / 20 °C

9.1: (DHQD)2PHAL; K₃[Fe(CN)6]; K₂CO₃ / potassium osmate dihydrate; K₂S₂O₈ / 2-methyl-propan-2-ol; H₂O / 16 h / cooling

10.1: 91 percent / PPTS / methanol; CH₂Cl₂ / 2.08 h / -78 - 20 °C

11.1: 59 percent / KHMDS / tetrahydrofuran; toluene / 16 h / cooling

12.1: 83 percent / KH / tetrahydrofuran; various solvent(s) / 2 h

13.1: 99 percent / TBAF / tetrahydrofuran / 16 h / 20 °C

14.1: 67 percent / Ph₃P; iodine; imidazole / benzene / 1 h / 20 °C

15.1: 70 percent / i-Pr₂NEt / acetonitrile / 48 h / 90 °C

16.1: KHMDS / toluene / 0.5 h / -78 °C

16.2: 26 percent / toluene / -78 - 20 °C

With pyridine; 1H-imidazole; dmap; mercury(II) diacetate; tetrabutyl ammonium fluoride; iodine; pyridinium p-toluenesulfonate; potassium hydride; potassium hexamethylsilazane; diisobutylaluminium hydride; potassium carbonate; Dess-Martin periodane; methanesulfonyl chloride; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; potassium hexacyanoferrate(III); potassium osmate(VI); dipotassium peroxodisulfate; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; tert-butyl alcohol; benzene; 1.1: Julia-Kocienski coupling / 3.1: Dess-Martin oxidation / 4.2: Wittig olefination / 16.2: Wittig olefination;
DOI:10.1021/jo062513f