dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

Base Information

Chemical Name:dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester
CAS No.:920509-72-4
Molecular Formula:C₂₇H₃₁Cl₂NO₂SSi
Molecular Weight:532.606
Hs Code.:

Synonyms:dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

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Chemical Property of dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

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Technology Process of dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

There total 4 articles about dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 920509-71-3
4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenol

: 16420-13-6
N,N-Dimethylthiocarbamoyl chloride

: 920509-72-4
dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; In N,N-dimethyl-formamide; at 25 ℃; for 18h;

Reference yield:

: 115150-58-8
2-(3,5-dichloro-4-hydroxyphenyl)ethanol

: 920509-72-4
dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine / dichloromethane / 18 h / 25 °C / Inert atmosphere

2: 1,4-diaza-bicyclo[2.2.2]octane / N,N-dimethyl-formamide / 18 h / 25 °C / Inert atmosphere

With 1,4-diaza-bicyclo[2.2.2]octane; triethylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm4019299

Reference yield:

: 14199-15-6
Methyl 4-hydroxyphenylacetate

: 920509-72-4
dimethylthiocarbamic acid O-{4-[2-(tert-butyldiphenylsilanyloxy)ethyl]-2,6-dichlorophenyl}ester

Guidance literature:: Multi-step reaction with 4 steps

1: diisobutylamine; sulfuryl dichloride / toluene / 1.5 h / 20 - 70 °C

2: lithium aluminium tetrahydride / tetrahydrofuran / 0.08 h / -10 °C / Inert atmosphere

3: triethylamine / dichloromethane / 18 h / 25 °C / Inert atmosphere

4: 1,4-diaza-bicyclo[2.2.2]octane / N,N-dimethyl-formamide / 18 h / 25 °C / Inert atmosphere

With 1,4-diaza-bicyclo[2.2.2]octane; lithium aluminium tetrahydride; diisobutylamine; sulfuryl dichloride; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jm4019299