(3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

Base Information

Chemical Name:(3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal
CAS No.:186886-71-5
Molecular Formula:C₂₄H₄₂O₃Si
Molecular Weight:406.681
Hs Code.:

Synonyms:(3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

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Chemical Property of (3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

Chemical Property:

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Technology Process of (3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

There total 1 articles about (3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: (4S,5S)-5-Benzyloxy-4,6-dimethyl-heptanal

: (-)-allyldiisopinocampheylborane

: 186886-71-5
(3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

Guidance literature:: With sodium hydroxide; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; lutidine; dihydrogen peroxide; Yield given. Multistep reaction;
DOI:10.1021/ja963800b

Reference yield: 84.0%

: 36850-80-3
[(1-methoxyvinyl)oxy]trimethylsilane

: 186886-71-5
(3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

: 186886-72-6
(3S,5S,8S,9S)-9-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-8,10-dimethyl-3-trimethylsilanyloxy-undecanoic acid methyl ester

Guidance literature:: With Carreira's catalyst;
DOI:10.1021/ja963800b

Reference yield:

: 186886-71-5
(3S,6S,7S)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6,8-dimethyl-nonanal

: 186886-73-7
(R)-6-[(2S,5S,6S)-6-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-5,7-dimethyl-octyl]-2,2-dimethyl-[1,3]dioxane-4-carbonitrile

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / Carreira's catalyst

2: 1.) DIBALH, 2.) 18-crown-6 / 3.) acetone

With 18-crown-6 ether; Carreira's catalyst; diisobutylaluminium hydride;
DOI:10.1021/ja963800b