tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

Base Information

Chemical Name:tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane
CAS No.:916260-47-4
Molecular Formula:C₃₄H₅₀O₃Si
Molecular Weight:534.855
Hs Code.:

<i>tert</i>-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

Synonyms:tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

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Chemical Property of tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

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Technology Process of tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

There total 6 articles about tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 916260-44-1
2-bromo-6-methyl-1,5-heptadiene

: 916260-47-4
tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1.1: t-BuLi / diethyl ether; pentane / 4 h / -78 - -20 °C

1.2: 90 percent / diethyl ether / 2 h / -78 °C

2.1: KH / tetrahydrofuran / 0.5 h / -40 - -20 °C

2.2: diethyl ether / 16 h / -20 - 0 °C

2.3: 61 percent / n-BuLi / petroleum ether; tetrahydrofuran / 3 h / -78 °C

3.1: Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 22 °C

4.1: 4.15 g / pyridinium tosylate / 22 °C

With tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium hydride; Dess-Martin periodane; In tetrahydrofuran; diethyl ether; dichloromethane; pentane;
DOI:10.1021/ja066336b

Reference yield:

: 916260-45-2
1-(tert-butyl-diphenyl-silanyloxy)-3,11-dimethyl-7-methylene-dodeca-2,10-dien-6-ol

: 916260-47-4
tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: KH / tetrahydrofuran / 0.5 h / -40 - -20 °C

1.2: diethyl ether / 16 h / -20 - 0 °C

1.3: 61 percent / n-BuLi / petroleum ether; tetrahydrofuran / 3 h / -78 °C

2.1: Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 22 °C

3.1: 4.15 g / pyridinium tosylate / 22 °C

With pyridinium p-toluenesulfonate; potassium hydride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja066336b

Reference yield:

: 916260-46-3
9-(tert-butyl-diphenyl-silanyloxy)-7-methyl-3-(4-methyl-pent-3-enyl)-nona-3,7-dien-1-ol

: 916260-47-4
tert-butyl-[7-(2,2-dimethoxy-ethyl)-3,11-dimethyl-dodeca-2,6,10-trienyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 22 °C

2: 4.15 g / pyridinium tosylate / 22 °C

With pyridinium p-toluenesulfonate; Dess-Martin periodane; In dichloromethane;
DOI:10.1021/ja066336b