(1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat

Base Information

• Chemical Name: (1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat
• CAS No.: 112104-79-7
• Molecular Formula: C₆H₁₅N*C₂₆H₂₄ClO₉P
• Molecular Weight: 648.09
• Mol file: 112104-79-7.mol

Synonyms:(1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat

Chemical Property of (1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat

There total 1 articles about (1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,2:3,5-Di-O-benzyliden-α-D-glucofuranose (22164-08-5) + triethylamine (121-44-8) + 2-chlorophenyl dichlorophosphate (15074-54-1) → (1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat (112104-79-7)

Guidance literature:

With 1,2,4-Triazole; In pyridine; for 0.5h;

DOI:10.1016/0008-6215(86)84003-4

Reference yield: 88.0%

1,2:3,5-Di-O-benzyliden-α-D-glucofuranose (22164-08-5) + (1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat (112104-79-7) → -(2-chlorphenyl)-phosphat (112135-72-5)

Guidance literature:

With 1-Mesitylensulfonsaeure-<1H>-3-nitrotriazol; In pyridine; for 0.75h; Ambient temperature;

DOI:10.1016/0008-6215(86)84003-4

Reference yield:

(1,2:3,5-Di-O-benzyliden-α-D-glucofuranose-6)-(2-chlorphenyl)-(triethylammonium)-phosphat (112104-79-7) → -natriumphosphat (112104-98-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / 1-Mesitylensulfonsaeure-<1H>-3-nitrotriazol / pyridine / 0.75 h / Ambient temperature

2: 93 percent / Pyridin-2-carbaldoxim, Tetramethylguanidine, NaOH / dioxane; H₂O / 72 h / Ambient temperature

With sodium hydroxide; 2-hydroxyiminomethyl-pyridine; 1,1,3,3-tetramethylguanidine; 1-Mesitylensulfonsaeure-<1H>-3-nitrotriazol; In 1,4-dioxane; pyridine; water;

DOI:10.1016/0008-6215(86)84003-4

upstream raw materials:

1,2:3,5-Di-O-benzyliden-α-D-glucofuranose

triethylamine

2-chlorophenyl dichlorophosphate

Downstream raw materials:

-(2-chlorphenyl)-phosphat

-natriumphosphat