benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

Base Information

Chemical Name:benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside
CAS No.:476313-24-3
Molecular Formula:C₃₈H₃₄ClNO₁₄
Molecular Weight:764.139
Hs Code.:

Synonyms:benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

Suppliers and Price of benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

There total 15 articles about benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 476313-37-8
benzyl 2-O-benzoyl-4-O-benzyl-3-O-chloroacetyl-6-O-(t-butylcarbonyl-2-nitrophenoxy-acetyl)-β-D-glucopyranoside

: 476313-24-3
benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

Guidance literature:: With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ja020781z

Reference yield:

: 476313-41-4
tert-butyl (4-methoxylcarbonylmethoxy)-3-nitro-benzoate

: 476313-24-3
benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 89 percent / LiOH / H₂O; methanol / 20 °C

2: 99 percent / PPh₃; DEAD / CH₂Cl₂ / 0 - 20 °C

3: 100 percent / TFA / CH₂Cl₂ / 3 h / 20 °C

With lithium hydroxide; triphenylphosphine; trifluoroacetic acid; diethylazodicarboxylate; In methanol; dichloromethane; water;
DOI:10.1021/ja020781z

Reference yield:

: 3011-34-5
4-hydroxy-3-nitrobenzaldehyde

: 476313-24-3
benzyl 2-O-benzoylbenzyl-3-O-chloroacetyl-6-O-(tert-butylcarbonyl-2-nitrophenoxyl-acetyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 64 percent / K₂CO₃ / acetonitrile / 70 °C

2: Jones reagent / acetone / 20 °C

3: 100 percent / DMAP; 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide / dimethylformamide / 0 - 20 °C

4: 89 percent / LiOH / H₂O; methanol / 20 °C

5: 99 percent / PPh₃; DEAD / CH₂Cl₂ / 0 - 20 °C

6: 100 percent / TFA / CH₂Cl₂ / 3 h / 20 °C

With dmap; lithium hydroxide; jones reagent; potassium carbonate; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; triphenylphosphine; trifluoroacetic acid; diethylazodicarboxylate; In methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile;
DOI:10.1021/ja020781z