(+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Base Information

Chemical Name:(+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene
CAS No.:114916-28-8
Molecular Formula:C₂₂H₂₁N₅O₄S₂
Molecular Weight:483.572
Hs Code.:

Synonyms:(+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

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Chemical Property of (+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

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Technology Process of (+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

There total 9 articles about (+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.5%

: 14210-25-4
5-Chloro-1-phenyltetrazole

: 114916-26-6
(+)-2-hydroxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

: 114916-28-8
(+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Guidance literature:: With potassium carbonate; In acetone; for 18h; Heating;
DOI:10.1016/S0040-4020(01)86895-2

Reference yield:

: 72856-73-6
2-methoxy-4-(methylsulfanyl)benzoic acid

: 114916-28-8
(+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Guidance literature:: Multi-step reaction with 9 steps

1: thionyl chloride / 2 h / Heating

2: 93 percent / triethylamine / toluene / Heating

3: 89 percent / tetrahydrofuran / 1 h / Heating

4: 23 percent / potassium permanganate / pyridine / 6 h / 50 - 60 °C

5: 50 percent / sodium hydroxide / methanol / 1 h / Heating

6: 52 percent / lithium aluminium hydride / tetrahydrofuran

7: 72 percent / H₂ / 5 percent palladised charcoal / methanol / 20 h

8: 86 percent / boron tribromide / CH₂Cl₂ / 2 h / Ambient temperature

9: 64.5 percent / potassium carbonate / acetone / 18 h / Heating

With sodium hydroxide; potassium permanganate; lithium aluminium tetrahydride; thionyl chloride; hydrogen; boron tribromide; potassium carbonate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane; acetone; toluene;
DOI:10.1016/S0040-4020(01)86895-2

Reference yield:

: 69883-78-9
2-methoxy-4-(methylthio)benzoyl chloride

: 114916-28-8
(+)-2-<5-(1-phenyl)-tetrazolo>-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Guidance literature:: Multi-step reaction with 8 steps

1: 93 percent / triethylamine / toluene / Heating

2: 89 percent / tetrahydrofuran / 1 h / Heating

3: 23 percent / potassium permanganate / pyridine / 6 h / 50 - 60 °C

4: 50 percent / sodium hydroxide / methanol / 1 h / Heating

5: 52 percent / lithium aluminium hydride / tetrahydrofuran

6: 72 percent / H₂ / 5 percent palladised charcoal / methanol / 20 h

7: 86 percent / boron tribromide / CH₂Cl₂ / 2 h / Ambient temperature

8: 64.5 percent / potassium carbonate / acetone / 18 h / Heating

With sodium hydroxide; potassium permanganate; lithium aluminium tetrahydride; hydrogen; boron tribromide; potassium carbonate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane; acetone; toluene;
DOI:10.1016/S0040-4020(01)86895-2