(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE

Base Information

• Chemical Name: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
• CAS No.: 65012-74-0
• Molecular Formula: C35H36P2Rh.ClO4
• Molecular Weight: 720.96
• Mol file: 65012-74-0.mol

Synonyms:(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE;(bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I);bicycloheptadiene(diphenylphosphino)butane rhodium ClO4

Chemical Property of (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE

Chemical Property:

• Melting Point: 210 °C (dec.)(lit.)
• PSA: 122.00000
• LogP: 8.45120

Purity/Quality:

97% ^*data from raw suppliers

(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE

There total 1 articles about (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

{Rh(NBD)2}ClO4 (60576-58-1) + (R,R)-chiraphos (74839-84-2) → [(2R,3R)-2,3-Bis(diphenylphosphino)butan](π-norbornadien)rhodium(I)-perchlorat (65012-74-0)

Guidance literature:

In tetrahydrofuran; dichloromethane; byproducts: norbornadiene; under N2, to soln. of reagents (0.75/0.723 mmol ratio) added during 4 hn-hexane, product partly pptd.; after 10 h crystd. time, filtered, washed with cold THF; elem. anal.;

upstream raw materials:

{Rh(NBD)2}ClO₄

(R,R)-chiraphos

Refernces