bicyclo[2.2.1]hepta-2,5-diene;[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;rhodium;perchlorate

Base Information

• Chemical Name: bicyclo[2.2.1]hepta-2,5-diene;[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;rhodium;perchlorate
• CAS No.: 65012-74-0
• Molecular Formula: C35H36P2Rh.ClO4
• Molecular Weight: 720.96
• European Community (EC) Number: 633-204-9
• DSSTox Substance ID: DTXSID70583557

Synonyms:65012-74-0;bicyclo[2.2.1]hepta-2,5-diene;[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;rhodium;perchlorate;DTXSID70583557;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate;(Bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphenylphosphino)butane)rh(i)cl04;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane] rhodium(I) perchlorate

Chemical Property of bicyclo[2.2.1]hepta-2,5-diene;[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;rhodium;perchlorate

Chemical Property:

• Melting Point: 210 °C (dec.)(lit.)
• PSA: 122.00000
• LogP: 8.45120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 7
• Exact Mass: 720.08323
• Heavy Atom Count: 43
• Complexity: 586

Purity/Quality:

97% ^*data from raw suppliers

(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C(C)P(C1=CC=CC=C1)C2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4.C1C2C=CC1C=C2.[O-]Cl(=O)(=O)=O.[Rh]
• Isomeric SMILES: C[C@@H]([C@H](C)P(C1=CC=CC=C1)C2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4.C1C2C=CC1C=C2.[O-]Cl(=O)(=O)=O.[Rh]

Technology Process of bicyclo[2.2.1]hepta-2,5-diene;[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;rhodium;perchlorate

There total 1 articles about bicyclo[2.2.1]hepta-2,5-diene;[(2S,3S)-3-diphenylphosphanylbutan-2-yl]-diphenylphosphane;rhodium;perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

{Rh(NBD)2}ClO4 (60576-58-1) + (R,R)-chiraphos (74839-84-2) → [(2R,3R)-2,3-Bis(diphenylphosphino)butan](π-norbornadien)rhodium(I)-perchlorat (65012-74-0)

Guidance literature:

In tetrahydrofuran; dichloromethane; byproducts: norbornadiene; under N2, to soln. of reagents (0.75/0.723 mmol ratio) added during 4 hn-hexane, product partly pptd.; after 10 h crystd. time, filtered, washed with cold THF; elem. anal.;

upstream raw materials:

{Rh(NBD)2}ClO₄

(R,R)-chiraphos

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 65012-74-0 (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE

Send

Send

Metric Ton KG G Pound L ML

Send

Send