N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide

Base Information

• Chemical Name: N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide
• CAS No.: 215297-21-5
• Molecular Formula: C₅₃H₄₄N₂O₁₀
• Molecular Weight: 868.94
• Mol file: 215297-21-5.mol

Synonyms:N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide

Chemical Property of N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide

There total 5 articles about N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

N-[2-(2-O-4,4'-dimethoxytritylethoxy)ethyl]-N'-[2-(2-O-tert-butyldimethylsilylethoxy)ethyl]-3,4,9,10-perylenetetracarboxylic diimide (215297-20-4) → N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide (215297-21-5)

Guidance literature:

With pyridine; hydrogen fluoride;

DOI:10.1021/ja0001714

Reference yield: 25.0%

2-(2-O-4,4'-dimethoxytritylethoxy)ethylamine + 3,4,9,10-perylene tetracarboxyxlic acid diimide (81-33-4) + 2-(2-Aminoethoxy)ethanol (929-06-6) → N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide (215297-21-5)

Guidance literature:

With pyridine; zinc diacetate; at 125 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c5ob00508f

Reference yield:

4,4'-dimethoxytrityl chloride (40615-36-9) → N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide (215297-21-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 69 percent / pyridine / 3 h

2: 50 percent / HF; pyridine

With pyridine; hydrogen fluoride; 1: tritylation / 2: desilylation;

DOI:10.1021/ja0001714

upstream raw materials:

N-[2-(2-O-4,4'-dimethoxytritylethoxy)ethyl]-N'-[2-(2-O-tert-butyldimethylsilylethoxy)ethyl]-3,4,9,10-perylenetetracarboxylic diimide

4,4'-dimethoxytrityl chloride

N-[2-(2-O-tert-butyldimethylsilylethoxy)ethyl]-N'-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide

N,N'-bis(2-(2-dimethyl-tert-butylsilyloxyethoxy)ethyl)perylene-3,4,9,10-tetracarboxylic acid bisimide