cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Base Information

Chemical Name:cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)
CAS No.:136050-00-5
Molecular Formula:C₄₂H₄₀O₂P₂RuS₂
Molecular Weight:803.928
Hs Code.:

Synonyms:cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

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Chemical Property of cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

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Technology Process of cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

There total 4 articles about cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 14564-35-3,15709-57-6,15709-73-6,29079-66-1,32240-63-4,36500-84-2
cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

: 811-51-8
sodium thioethylate

: 136050-16-3
cis,cis,trans-Cl((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

: 136050-00-5
cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Guidance literature:: In tetrahydrofuran; under Ar at room temp. for 10-15 min with excess NaSEt; (1)H and (31)P NMR detn.;

Reference yield: 16.0%

: RuCl₂*3H₂O

: 811-51-8
sodium thioethylate

: 14564-35-3,15709-57-6,15709-73-6,29079-66-1,32240-63-4,36500-84-2
cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

: 136050-11-8
{(triphenylphosphine)(carbonyl)2ruthenium(μ2-ethanethiolato)(μ3-ethanethiolato)sodium(THF)}2

: 136050-16-3
cis,cis,trans-Cl((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

: 136050-00-5
cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Guidance literature:: With P(C₆H₅)3; CO; In methanol; under N2, refluxinf Ru salt and PPh3 in MeOH, cooling to 20°C, addn. of NaSEt and introducing CO at 1 atm for 30 min; vac. distn., (31)P NMR detn.;

Reference yield:

: 14564-35-3,15709-57-6,15709-73-6,29079-66-1,32240-63-4,36500-84-2
cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

: 811-51-8
sodium thioethylate

: 136050-00-5
cis,cis,trans-bis(ethanethiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Guidance literature:: In acetone; byproducts: PPh3; soln. under 1 atm CO at 20°C with stirring overnight; filtn., concn. of filtrate in vac., addn. of MeOH, 2 h at 0°C, filtn. of ppt.;