1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate

Base Information

Chemical Name:1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate
CAS No.:122948-58-7
Molecular Formula:C₉H₆BrF₃O₃S
Molecular Weight:331.11
Hs Code.:
DSSTox Substance ID:DTXSID301199413

Synonyms:YIIMBLZQHCISNG-UHFFFAOYSA-N;DTXSID301199413;1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate;1-(4-Bromophenyl)ethenyl 1,1,1-trifluoromethanesulfonate;122948-58-7

Suppliers and Price of 1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate

Chemical Property:

XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:3
Exact Mass:329.91731
Heavy Atom Count:17
Complexity:377

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=C(C1=CC=C(C=C1)Br)OS(=O)(=O)C(F)(F)F

Technology Process of 1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate

There total 4 articles about 1-(4-Bromophenyl)ethenyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 99-90-1
para-bromoacetophenone

: 122948-58-7
1-(4-bromophenyl)vinyl trifluoromethanesulfonate

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; In dichloromethane; at 0 - 20 ℃; for 16h;
DOI:10.1002/anie.201608507

Reference yield: 72.0%

: 766-96-1
4-bromo-1-ethynylbenzene

: 1493-13-6
trifluorormethanesulfonic acid

: 122948-58-7
1-(4-bromophenyl)vinyl trifluoromethanesulfonate

Guidance literature:: With trimethylsilylazide; In dichloromethane; at 20 ℃; for 1h; chemoselective reaction;
DOI:10.1021/acs.orglett.9b01576

Reference yield:

: 766-96-1
4-bromo-1-ethynylbenzene

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 122948-58-7
1-(4-bromophenyl)vinyl trifluoromethanesulfonate

Guidance literature:: With zinc trifluoromethanesulfonate; In chloroform-d1; at 20 ℃; for 4.5h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol501852n