((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Base Information

Chemical Name:((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate
CAS No.:111718-47-9
Molecular Formula:C₁₆H₁₈O₆
Molecular Weight:306.315
Hs Code.:

Synonyms:((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Suppliers and Price of ((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

There total 11 articles about ((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 75414-38-9
(6S)-4-benzoyloxy-6-benzoyloxymethyl-2H-pyran-3(6H)-one

: 67-64-1
acetone

: 111718-49-1
((2S,5R)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

: 111718-47-9
((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; water; at -20 ℃; for 2h;
DOI:10.1016/j.tetasy.2008.01.019

Reference yield: 57.0%

: 1451079-91-6
((2S,5S)-5-allyl-5-hydroxy-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

: 111718-47-9
((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Guidance literature:: With oxygen; copper(l) chloride; palladium dichloride; In water; N,N-dimethyl-formamide; at 20 ℃; for 12h; under 760.051 Torr;
DOI:10.1016/j.tet.2013.07.048

Reference yield:

: 82569-81-1
1,5-anhydro-3,4,6-tri-O-benzoyl-D-fructose oxime

: 111718-47-9
((2S,5S)-5-hydroxy-5-(2-oxopropyl)-4-oxo-tetrahydro-2H-pyran-2-yl)methyl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 2 N HCl / acetic anhydride; acetonitrile / 10 h / Ambient temperature

2: NaHCO₃ / 6 h

3: 1) -78 deg C, 10 min, THF; 2) H₂O, 2 h, -20 deg C

With hydrogenchloride; sodium hydrogencarbonate; In acetic anhydride; acetonitrile;