benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

Base Information

Chemical Name:benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside
CAS No.:1264438-99-4
Molecular Formula:C₃₁H₄₆INO₅Si
Molecular Weight:667.7
Hs Code.:

Synonyms:benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

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Chemical Property of benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

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Technology Process of benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

There total 1 articles about benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 50908-14-0
benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-α-D-glucopyranoside

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 1264438-99-4
benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1016/j.tetlet.2010.11.078

Reference yield:

: 1264438-99-4
benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

: 1264439-47-5
C₃₁H₄₅NO₅Si

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 70 ℃; for 10h;
DOI:10.1016/j.tetlet.2010.11.078

Reference yield:

: 1264438-99-4
benzyl 2-acetamido-3-O-benzyl-2,6-dideoxy-6-iodo-4-O-triisopropylsilyl-α-D-glucopyranoside

: benzyl 2-acetamido-3-O-benzyl-4-methoxyimino-2,4,6-trideoxy-α-L-idopyranoside

: 1264439-12-4
benzyl 2-acetamido-3-O-benzyl-4-methoxyimino-2,4,6-trideoxy-α-L-idopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: potassium tert-butylate / tetrahydrofuran / 10 h / 70 °C

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 °C

3: Wilkinson's catalyst; hydrogen / ethanol; benzene / 3 h / 20 °C / 760.05 Torr

4: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 17 h / 20 °C

5: sodium hydrogencarbonate / methanol / 17 h / 65 °C

With Wilkinson's catalyst; potassium tert-butylate; tetrabutyl ammonium fluoride; hydrogen; sodium hydrogencarbonate; Dess-Martin periodane; In tetrahydrofuran; methanol; ethanol; dichloromethane; benzene;
DOI:10.1016/j.tetlet.2010.11.078