(S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

Base Information

Chemical Name:(S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane
CAS No.:176094-54-5
Molecular Formula:C₁₀H₁₂O₅S
Molecular Weight:244.268
Hs Code.:

Synonyms:(S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

Chemical Property:

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Technology Process of (S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

There total 3 articles about (S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 13071-59-5,17325-85-8,56552-80-8,4799-67-1
3-benzyloxypropan-1,2-diol

: 176094-54-5
(S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

Guidance literature:: 3-benzyloxypropan-1,2-diol; With thionyl chloride; In tetrachloromethane; for 1h; Reflux;

With ruthenium trichloride; sodium periodate; In water; acetonitrile; at 0 ℃; for 1h;
DOI:10.3998/ark.5550190.0011.913

Reference yield:

: 4704-76-1
4-(benzyloxymethyl)-1,3-dioxo-2-thiolane 2-oxide

: 176094-54-5
(S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

Guidance literature:: With ruthenium(IV) oxide; sodium periodate; In water; acetonitrile; Petroleum ether; at 20 ℃; for 24h; Yield given;
DOI:10.1055/s-1996-4193

Reference yield:

: 14593-43-2
benzyl allyl ether

: 176094-54-5
(S)-4-(Benzyloxymethyl)-2,2-dioxo-1,3,2-dioxathiolane

Guidance literature:: Multi-step reaction with 3 steps

1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / water; tert-butyl alcohol; acetone / 20 °C / Cooling with ice

2: triethylamine; thionyl chloride / dichloromethane / Inert atmosphere

3: sodium periodate; ruthenium(III) chloride trihydrate / water; acetonitrile / 1 h

With sodium periodate; osmium(VIII) oxide; thionyl chloride; ruthenium(III) chloride trihydrate; 4-methylmorpholine N-oxide; triethylamine; In dichloromethane; water; acetone; acetonitrile; tert-butyl alcohol;
DOI:10.1021/acs.orglett.6b01745