endo-2-norbornene-5-yl-trimethyl tin

Base Information

• Chemical Name: endo-2-norbornene-5-yl-trimethyl tin
• CAS No.: 21957-51-7
• Molecular Formula: C₁₀H₁₈Sn
• Molecular Weight: 256.963
• Mol file: 21957-51-7.mol

Synonyms:endo-2-norbornene-5-yl-trimethyl tin

Chemical Property of endo-2-norbornene-5-yl-trimethyl tin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of endo-2-norbornene-5-yl-trimethyl tin

There total 5 articles about endo-2-norbornene-5-yl-trimethyl tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-Iodonortricyclene (36071-35-9) → norborn-2-ene (498-66-8) + nortricyclane (279-19-6) + 3-nortricyclyltrimethyltin (21942-28-9) + endo-2-norbornene-5-yl-trimethyl tin (21957-51-7)

Guidance literature:

With trimethylstannylsodium; In tetrahydrofuran; at 0 ℃; Product distribution; Mechanism; various amounts of the tert-butylamine and dicyclohexylphosphine;

DOI:10.1021/jo00319a002

Reference yield:

exo-5-Chloro-2-norbornene (3721-19-5) → norborn-2-ene (498-66-8) + nortricyclane (279-19-6) + 3-nortricyclyltrimethyltin (21942-28-9) + endo-2-norbornene-5-yl-trimethyl tin (21957-51-7)

Guidance literature:

With trimethylstannylsodium; In tetrahydrofuran; at 23 ℃; Product distribution; Mechanism; various amounts of the tert-butylamine and dicyclohexylphosphine;

DOI:10.1021/jo00319a002

Reference yield:

(+/-)-5exo-bromo-norborn-2-ene (5889-54-3) → norborn-2-ene (498-66-8) + nortricyclane (279-19-6) + 3-nortricyclyltrimethyltin (21942-28-9) + endo-2-norbornene-5-yl-trimethyl tin (21957-51-7)

Guidance literature:

With trimethylstannylsodium; In tetrahydrofuran; at 0 ℃; Product distribution; Mechanism; various amounts of tert-butylamine and dicyclohexylphosphorane;

DOI:10.1021/jo00319a002

upstream raw materials:

Nortricyclylbromid

3-Iodonortricyclene

exo-5-Chloro-2-norbornene

(+/-)-5exo-bromo-norborn-2-ene

Refernces