[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

Base Information

Chemical Name:[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]
CAS No.:1002720-60-6
Molecular Formula:C₃₉H₆₀Cl₂LuN₃O₃
Molecular Weight:864.797
Hs Code.:

[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl<sub>2</sub>(THF)3]

Synonyms:[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

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Chemical Property of [(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

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Technology Process of [(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

There total 1 articles about [(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 928797-95-9
1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-imine

: 10099-66-8
lutetium(III) chloride

: 1002720-60-6
[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

Guidance literature:: With trimethylsilylmethyl lithium; In tetrahydrofuran; mixt. of LuCl3 and LiCH2SiMe3 treated with THF; stirred for 2 h; soln. of ligand in THF added; stirred for 12 h; solvent evapd.; repeatedly extd. with pentane; recrystd. from THF-pentane at -30°C; elem. anal.;
DOI:10.1021/ic900503q

Reference yield: 97.0%

: 1002720-60-6
[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

: 1822-00-0
trimethylsilylmethyllithium

: 1210396-00-1
[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)Lu(trimethylsilylmethyl)2(THF)2]

Guidance literature:: In tetrahydrofuran; (Schlenk) to a THF-soln. of rare-metal complex LiCH2Si(CH3)3 in THF was added dropwise at ambient temp., the mixt. was stirred for 12 h; the solvent was evapd., extd. with pentane, filtered, evapd., crystd. from THF/pentane at -30°C; elem. anal.;
DOI:10.1021/ic9024052

Reference yield: 97.0%

: 1002720-60-6
[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl₂(THF)3]

: 94348-92-2
potassium pentamethylcyclopentadiene

: 1210396-02-3
[(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-iminato)LuCl(pentamethylcyclopentadienyl)(THF)]

Guidance literature:: In tetrahydrofuran; (Schlenk) KC5(CH3)5 in THF was added dropwise to a soln. of rare-metal complex in THF at ambient temp., the mixt. was stirred for 12 h; evapd., extd. with pentane/toluene, filtered, evapd., crystd. from THF/pentane at -30°C; elem. anal.;
DOI:10.1021/ic9024052