(Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

Base Information

Chemical Name:(Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane
CAS No.:737796-39-3
Molecular Formula:C₃₃H₃₆OSi
Molecular Weight:476.734
Hs Code.:

Synonyms:(Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

Suppliers and Price of (Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

Chemical Property:

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Technology Process of (Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

There total 7 articles about (Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 427879-53-6
(Z)-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-yl]methanol

: 737796-39-3
(Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 23 ℃; for 1h;
DOI:10.1021/ol049369+ DOI:10.1021/ja0561340

Reference yield:

: 87736-74-1
4-(tert-butyldimethylsiloxymethyl)bromobenzene

: 353739-79-4
(Z)-1-[2-(4-bromo-phenyl)]-biphenyl-ethene

: 737796-39-3
(Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

Guidance literature:: 4-(tert-butyldimethylsiloxymethyl)bromobenzene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 1h;

With zinc(II) chloride; In tetrahydrofuran; pentane; at 23 ℃; for 1.5h;

(Z)-1-[2-(4-bromo-phenyl)]-biphenyl-ethene; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; pentane; for 18h; Further stages.; Heating;
DOI:10.1021/ja017577g

Reference yield:

: 873-75-6
4-bromobenzenemethanol

: 737796-39-3
(Z)-[4'-(2-biphenyl-4-ylvinyl)-biphenyl-4-ylmethoxy]-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 95 percent / imidazole / CH₂Cl₂ / 23 °C

2.1: tert-butyllithium / tetrahydrofuran; pentane / 1 h / -78 °C

2.2: zinc chloride / tetrahydrofuran; pentane / 1.5 h / 23 °C

2.3: tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran; pentane / 18 h / Heating

With 1H-imidazole; tert.-butyl lithium; In tetrahydrofuran; dichloromethane; pentane;
DOI:10.1021/ma020155m