Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate

Base Information

Chemical Name:Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate
CAS No.:117539-41-0
Molecular Formula:C₁₃H₁₆O₂
Molecular Weight:204.269
Hs Code.:
DSSTox Substance ID:DTXSID101275586

Synonyms:Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate;SCHEMBL10296054;DTXSID101275586;117539-41-0

Suppliers and Price of Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate

Chemical Property:

XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:204.115029749
Heavy Atom Count:15
Complexity:225

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C=C(C)CC1=CC=CC=C1
Isomeric SMILES:CCOC(=O)/C=C(/C)\CC1=CC=CC=C1

Technology Process of Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate

There total 4 articles about Ethyl (2Z)-3-methyl-4-phenyl-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 103-79-7,136675-26-8
1-phenyl-acetone

: ethyl (E)-3-methyl-4-phenylbut-2-enoate

: 117539-41-0
ethyl (Z)-3-methyl-4-phenylbut-2-enoate

Guidance literature:: diethoxyphosphoryl-acetic acid ethyl ester; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.583333h; Inert atmosphere;

1-phenyl-acetone; In tetrahydrofuran; mineral oil; Inert atmosphere; Reflux;
DOI:10.1002/chem.201200907

Reference yield:

: 4341-76-8
Ethyl 2-butynoate

: ethyl (E)-3-methyl-4-phenylbut-2-enoate

: 117539-41-0
ethyl (Z)-3-methyl-4-phenylbut-2-enoate

Guidance literature:: With copper(l) iodide; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; at -78 - -40 ℃; for 2.16667h; Overall yield = 62 %; stereoselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.201601446

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 92511-62-1
ethyl 3-methyl-4-(tributylstannyl)-2-butenoate

: 75321-72-1
ethyl (E,Z)-3-methyl-4-phenylbut-2-enoate

: 75321-71-0
3-methyl-4-phenyl-but-3-enoic acid ethyl ester

: 117539-41-0
ethyl (Z)-3-methyl-4-phenylbut-2-enoate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In benzene; for 24h; Yield given. Yields of byproduct given; Heating;
DOI:10.1021/jo00297a030