2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane

Base Information

• Chemical Name: 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane
• CAS No.: 145950-08-9
• Molecular Formula: C₂₀H₂₀O₃S₂
• Molecular Weight: 372.509
• Mol file: 145950-08-9.mol

Synonyms:2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane

Chemical Property of 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane

There total 5 articles about 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1-ethynyl-2-(phenylsulfonyl)cyclohexanol + benzenesulfenyl chloride (931-59-9) → 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane (145950-08-9)

Guidance literature:

With triethylamine;

DOI:10.1021/jo00072a019

Reference yield:

1-ethynyl-2-(phenylsulfinyl)cyclohexanol → 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane (145950-08-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / 30percent H₂O₂ / acetic acid / 1 h / Heating

2: 76 percent / NEt₃

With dihydrogen peroxide; triethylamine; In acetic acid;

DOI:10.1021/jo00072a019

Reference yield:

thiophenol (108-98-5) → 2-<2-(phenylsulfinyl)-ethylidene>-1-(phenylsulfonyl)cyclohexane (145950-08-9)

Guidance literature:

Multi-step reaction with 3 steps

1: O₂

2: oxone

3: Et₃N / CH₂Cl₂

With Oxone; oxygen; triethylamine; In dichloromethane;

DOI:10.1016/S0040-4039(00)60172-7

upstream raw materials:

2-Benzenesulfonyl-1-ethynyl-cyclohexanol

benzenesulfenyl chloride

thiophenol

2-Benzenesulfinyl-1-ethynyl-cyclohexanol

Downstream raw materials:

trans-2-<2-(phenylsulfinyl)ethenyl>-1-(phenylsulfonyl)cyclohexene

trans-2-<2-(phenylsulfonyl)ethenyl>-1-(phenylsulfonyl)cyclohexene