Silver perchlorate hydrate

Base Information

• Chemical Name: Silver perchlorate hydrate
• CAS No.: 14242-05-8
• Molecular Formula: Ag. Cl H O4 . H2 O
• Molecular Weight: 225.334
• Hs Code.: 28432900
• European Community (EC) Number: 628-990-5,677-705-0
• DSSTox Substance ID: DTXSID10931437
• Mol file: 14242-05-8.mol

Synonyms:Silver perchlorate hydrate;14242-05-8;331717-44-3;silver;perchlorate;hydrate;Silverperchloratemono hydrate;MFCD00149128;Silver perchlorite;silver perchloric acid;DTXSID10931437;Silver perchlorate hydrate, 99%;Silver(I) perchlorate monohydrate;AKOS015909762;Silver(1+) perchlorate--water (1/1/1);Silver perchlorate monohydrate, 99.999% trace metals basis

Chemical Property of Silver perchlorate hydrate

Chemical Property:

• Appearance/Colour: WHITE CRYSTALS OR CRYSTALLINE POWDER
• Melting Point: 43℃
• PSA: 83.50000
• Density: 2,8g/cm3
• LogP: 0.15000
• Storage Temp.: Refrigerator (+4°C)
• Sensitive.: Light Sensitive & Hygroscopic
• Water Solubility.: Soluble in water and organic solvents.
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 223.86417
• Heavy Atom Count: 7
• Complexity: 95.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Silver Perchlorate Hydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O,C
• Hazard Codes: O,C
• Statements: 8-34-1
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O.[O-]Cl(=O)(=O)=O.[Ag+]
• Uses: Silver perchlorate can be used in the manufacturing of explosives. It is generally used as a source of silver ions during silver nanoparticles synthesis. It is used as a catalyst in organic chemistry. Silver Perchlorate Hydrate is used in the hydroxylation of hexabromotetrahydronaphthalene.

Technology Process of Silver perchlorate hydrate

There total 2 articles about Silver perchlorate hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silver perchlorate → silver perchlorate monohydrate (14242-05-8)

Guidance literature:

With Ag₂CO₃ or Ag₂O; In water; addition of a small excess of Ag2CO3 or Ag2O to a solution of AgClO4 in H2O, filtration and evaporation;; formation of the hydrate on cooling down;;

DOI:10.1021/ja01289a027

Reference yield:

water (7732-18-5) + silver perchlorate → silver perchlorate monohydrate (14242-05-8)

Guidance literature:

formation of the hydrate at 25°C;;

Reference yield: 94.0%

silver perchlorate monohydrate (14242-05-8) + OsCl(NO)(CS)(P(C6H5)3)2 (105032-94-8) → Os(NO)(CO)(CS)(P(C6H5)3)2(1+)*ClO4(1-)=[Os(NO)(CO)(CS)(P(C6H5)3)2]ClO4 (105033-00-9)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; ethanol; byproducts: AgCl; (N2); a soln. of OsCl(NO)(CS)(PPh3)2 in THF is satd. with CO, treated with a soln. of AgClO4*H2O in ethanol, the suspn. is stirred for 10 min and placed under 2 atm of CO; vessel is vented, diln. (CH2Cl2), filtration, crystn. (evapn. with subsequent addn. of hexane), filtration, washing (hexane), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(00)99663-3

upstream raw materials:

water

Downstream raw materials:

silver

Ag(dap)2⁽¹⁺⁾

bis(tricyclohexylphosphine)silver(I)perchlorate

trans-chlorobis{(1,4-dioxane-2-ylmethyl)diphenylphosphane-P;O',P'}palladium(II) perchlorate