(5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

Base Information

Chemical Name:(5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)
CAS No.:80584-26-5
Molecular Formula:C₄₈H₃₆CrN₄O
Molecular Weight:736.836
Hs Code.:

Synonyms:(5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

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Chemical Property of (5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

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Technology Process of (5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

There total 7 articles about (5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: C₂₀H₈N₄(C₆H₄CH₃)4Cr(OH)(H₂O)*H₂O

: 84174-28-7
nitrido{5,10,15,20-tetrakis(4-methylphenyl)porphinato}chromium(V)

: 80584-26-5
(5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

Guidance literature:: With NH₃; NaOCl; In ethanol; dichloromethane; water; byproducts: H2O, NaCl; To soln. of complex in CH2Cl2/EtOH is added aq. NH3 and aq. NaOCl, mixt. was stirred for 3-4 h.; Mixt. is washed with H2O, organic phase is sepd. and evapd. in vac., residue is dissolved in toluene and chromd., soln. is filtered and dried in vac., residue is recrystd. from benzene; elem. anal.;

Reference yield:

: 43145-39-7
chlorochromium(III) meso-tetrakis(4-methylphenyl)porphyrinate

: 79919-63-4
(2,3,7,8,12,13,17,18-octaethylporphyrinato)oxochromium(IV)

: 65024-11-5
chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato)chromium(III)

: 80584-26-5
(5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

Guidance literature:: In benzene-d6; react. at various temps.; (1)H-NMR and UV-vis monitoring of react.; Kinetics;

Reference yield:

: (meso-tetra-p-tolylporphyrinato^(2-))Cr(C₆H₅)

: 80584-26-5
(5,10,15,20-tetra-p-tolylporphyrinato)oxochromium(IV)

Guidance literature:: With oxygen; In chloroform-d1; byproducts: C6H5D; (TTP)Cr(C6H5) dissolved in CDCl3 under N2 in the dark; O2 added via syringe; NMR tube shaken for 10 s and immediately cooled in a dry ice/acetone bath; warming to -45°C; mechanism discussed;; not isolated, detected by (1)H-NMR spectroscopy;;
DOI:10.1021/om00025a011