thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

Base Information

• Chemical Name: thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside
• CAS No.: 212246-68-9
• Molecular Formula: C₂₁H₃₃N₃O₅Si
• Molecular Weight: 435.596

Synonyms:thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

Chemical Property of thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

There total 1 articles about thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

benzaldehyde dimethyl acetal (1125-88-8) + thexyldimethylsilyl 2-azido-2-deoxy-β-D-galactopyranoside (212246-67-8) → thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside (212246-68-9)

Guidance literature:

With toluene-4-sulfonic acid; In N,N-dimethyl-formamide; at 50 ℃; for 5h;

DOI:10.1080/07328300500176312

Reference yield: 94.0%

benzoyl chloride (98-88-4) + thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside (212246-68-9) → Benzoic acid (2S,4aR,6S,7R,8R,8aR)-7-azido-6-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester (640273-58-1)

Guidance literature:

With pyridine;

DOI:10.1021/ol035882w

Reference yield: 89.0%

Acetic acid (2S,4aR,7R,8S,8aS)-7-acetoxy-2-phenyl-6-(2,2,2-trichloro-acetimidoyloxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester (866890-15-5) + thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside (212246-68-9) → thexyldimethylsilyl (2,3-di-O-acetyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside (866890-16-6)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1080/07328300500176312

upstream raw materials:

benzaldehyde dimethyl acetal

thexyldimethylsilyl 2-azido-2-deoxy-β-D-galactopyranoside

Downstream raw materials:

Benzoic acid (2S,4aR,6S,7R,8R,8aR)-7-azido-6-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

thexyldimethylsilyl (2,3-di-O-acetyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

thexyldimethylsilyl (2,3-di-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

methyl (2,3-di-O-acetyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 212246-68-9 thexyldimethylsilyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send