chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II)

Base Information

• Chemical Name: chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II)
• CAS No.: 144749-20-2
• Molecular Formula: C₂₃H₁₉ClNPPtS
• Molecular Weight: 602.983
• Mol file: 144749-20-2.mol

Synonyms:chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II)

Chemical Property of chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II)

There total 1 articles about chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + {Pt(C5H4NS)2(P(C6H5)3)2} (218960-61-3,86431-36-9) → chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II) (144749-20-2)

Guidance literature:

In benzene; (N2); suspension stirred for 3 h at room temp.; soln. filtered, hexane added, filtered, washed with hexane and ether, recrystd. from benzene-hexane; elem. anal.;

DOI:10.1016/S0020-1693(00)82963-1

Reference yield: 77.0%

2-Sulfanylpyridine (2637-34-5,73018-10-7) + chloro(pyridine-2-thiolato)(triphenylphosphine)platinum(II) (144749-20-2) → {Pt(C5H4NS)2(P(C6H5)3)} (144772-08-7)

Guidance literature:

With NaOCH₃; In tetrahydrofuran; (N2); to soln. of C5H4NSH in THF added NaOCH3 in methanol, soln. added to (PtCl(C5H4NS)(PPh3)) in THF, stirred for 2 h; solvent evapd. to dryness, solid extracted with benzene, hexane added, standed overnight, filtered, washed with ether, dried in vacuo; elem. anal.;

DOI:10.1016/S0020-1693(00)82963-1

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

{Pt(C₅H₄NS)2(P(C₆H₅)3)2}

Downstream raw materials:

{Pt(C₅H₄NS)2(P(C₆H₅)3)}