2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

Base Information

Chemical Name:2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate
CAS No.:1309789-73-8
Molecular Formula:C₃₇H₃₅Cl₃N₄O₇
Molecular Weight:754.067
Hs Code.:

Synonyms:2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

Suppliers and Price of 2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

There total 2 articles about 2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 1309789-72-7
phenyl 2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside

: 545-06-2
trichloroacetonitrile

: 1309789-73-8
2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

Guidance literature:: phenyl 2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside; With N-iodo-succinimide; trifluorormethanesulfonic acid; In water; acetone; at 20 ℃; for 2h;

trichloroacetonitrile; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/jo200588u

Reference yield:

: 127299-77-8
phenyl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside

: 289712-58-9
2-(azidomethyl)benzoyl chloride

: 1309789-73-8
2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1.1: pyridine / 2 h / 20 °C

2.1: N-iodo-succinimide; trifluorormethanesulfonic acid / water; acetone / 2 h / 20 °C

2.2: 0.5 h / 0 °C

With pyridine; N-iodo-succinimide; trifluorormethanesulfonic acid; In water; acetone;
DOI:10.1021/jo200588u

Reference yield: 94.0%

: 1309789-70-5
phenyl 2-O-benzoyl-3,4-di-O-benzyl-1-thio-α-D-mannopyranoside

: 1309789-73-8
2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

: 1309789-74-9
phenyl (2-O-(2-azidomethylbenzoyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-2-O-benzoyl-3,4-di-O-benzyl-1-thio-α-D-mannopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In diethyl ether; at -30 ℃; for 0.5h; Molecular sieve;
DOI:10.1021/jo200588u