ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

Base Information

Chemical Name:ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex
CAS No.:133372-94-8
Molecular Formula:C₅₀H₅₀Cl₂O₂P₂Ru
Molecular Weight:916.869
Hs Code.:

ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl<sub>2</sub> complex

Synonyms:ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

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Chemical Property of ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

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Technology Process of ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

There total 1 articles about ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 3383-21-9
3,5-di-tert-butyl-o-benzoquinone

: 133372-94-8
ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

Guidance literature:: In dichloromethane; addn. of CH2Cl2 to a mixt. of Ru complex and DBBQ under N2, color change of soln. to blue within minutes, stirred for 5 h; hexane layered over soln. to induce crystn., N2 passed over the soln. for slow evapn.; two isomers in 3:1 ratio (1H-NMR);

Reference yield: 74.0%

: 1020-31-1,122983-47-5,881376-69-8
3,5-Di-tert-butylcatechol

: 133372-94-8
ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

: 133443-61-5,133372-97-1,133443-60-4,139629-96-2
ruthenium(III) (triphenylphosphine)2 (3,5-di-tert-butylsemiquinone)2 complex

Guidance literature:: With triethyl amine; In dichloromethane; addn. of CH2Cl2 to a mixt. of Ru complex and H2DBCat, addn. of triethyl amine, stirred for 4 h; evapn. of solvent, solid residue dissolved in benzene, filtration, chromy. (alumina/benzene) of filtrate, evapn. of major blue-green fraction;

Reference yield: 44.0%

: 133372-94-8
ruthenium(III) (triphenylphosphine)2 3,5-di-tert-butylsemiquinone Cl₂ complex

: 1198-55-6
o-chloranil

: ruthenium(III) (triphenylphosphine)2 (tetrachloro-1,2-semiquinone)2 dichloromethane solvate

: 133443-62-6,133372-95-9
ruthenium(III) (triphenylphosphine)2 (3,5-di-tert-butylsemiquinone) (tetrachloro-1,2-semiquinone)

Guidance literature:: With CH₂Cl₂; triethyl amine; In dichloromethane; addn. of CH2Cl2 to a mixt. of Ru complex and H2Cl4Cat under N2, addn. of triethylamine, stirred for 20 h; evapn. of solvent under reduced pressure, solid residue dissolved in benzene, filtered, chromy. (alumina/benzene) of filtrate, second band (blue-green) gave Ru(PPh3)2(Cl4SQ)2, third band (purple) gave Ru(PPh3)2(DBSQ)(Cl4SQ)(two isomers, 1H-NMR);