(R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

Base Information

Chemical Name:(R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane
CAS No.:528521-80-4
Molecular Formula:C₃₂H₂₈F₃O₅PS
Molecular Weight:612.606
Hs Code.:

Synonyms:(R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

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Technology Process of (R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

There total 3 articles about (R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 528521-76-8
(R)-7-di(p-methoxyphenyl)phosphinyl-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

: 528521-80-4
(R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

Guidance literature:: With trichlorosilane; N-ethyl-N,N-diisopropylamine; In toluene; at 110 ℃;
DOI:10.1021/ja029907i

Reference yield:

: 15754-51-5
bis(4-methoxyphenyl)phosphine oxide

: 528521-80-4
(R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / Pd(OAc)2; 1,4-bis(diphenylphosphino)butane; diisopropylethylamine / dimethylsulfoxide / 100 °C

2: 75 percent / Cl₃SiH; diisopropylethylamine / toluene / 110 °C

With palladium diacetate; trichlorosilane; N-ethyl-N,N-diisopropylamine; 1,4-di(diphenylphosphino)-butane; In dimethyl sulfoxide; toluene;
DOI:10.1021/ja029907i

Reference yield:

: (R)-7,7'-bis(trifluoromethanesulfonyloxy)-1,1‘-spirobiindane

: 528521-80-4
(R)-7-di(p-methoxyphenyl)phosphino-7'-trifluoromethanesulfonyloxy-1,1'-spirobiindane

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / Pd(OAc)2; 1,4-bis(diphenylphosphino)butane; diisopropylethylamine / dimethylsulfoxide / 100 °C

2: 75 percent / Cl₃SiH; diisopropylethylamine / toluene / 110 °C

With palladium diacetate; trichlorosilane; N-ethyl-N,N-diisopropylamine; 1,4-di(diphenylphosphino)-butane; In dimethyl sulfoxide; toluene;
DOI:10.1021/ja029907i