1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

Base Information

Chemical Name:1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate
CAS No.:902778-24-9
Molecular Formula:C₂₀H₂₅ClO₇
Molecular Weight:412.867
Hs Code.:

Synonyms:1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

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Technology Process of 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

There total 1 articles about 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 2912-62-1
α-chlorophenylacetyl chloride

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 902778-24-9
1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/j.tet.2006.04.045

Reference yield:

: 902778-24-9
1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

: 100-46-9
benzylamine

: 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl (R)-N-benzyl-α-phenylglycinate

: 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl (S)-N-benzyl-α-phenylglycinate

Guidance literature:: With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; Title compound not separated from byproducts;
DOI:10.1016/j.tet.2006.04.045

Reference yield:

: 902778-24-9
1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate

: 100-46-9
benzylamine

: 121440-91-3
methyl N-benzyl-(R)-α-phenylglycinate

: 670278-81-6
methyl N-benzyl-(S)-α-phenylglycinate

Guidance literature:: 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-O-yl α-chloro-α-phenylacetate; benzylamine; With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 12h;

With triethylamine; In methanol; for 48h; Title compound not separated from byproducts;
DOI:10.1016/j.tet.2006.04.045