9-Methyl-9-phenylsulfanyl-9H-fluorene

Base Information

• Chemical Name: 9-Methyl-9-phenylsulfanyl-9H-fluorene
• CAS No.: 102001-98-9
• Molecular Formula: C₂₀H₁₆S
• Molecular Weight: 288.413
• European Community (EC) Number: 682-962-7
• Mol file: 102001-98-9.mol

Synonyms:(9-Methyl-9H-fluoren-9-yl)(phenyl)sulfane;102001-98-9;9-METHYL-9-PHENYLSULFANYL-9H-FLUORENE;SCHEMBL18235708;AKOS024331715

Chemical Property of 9-Methyl-9-phenylsulfanyl-9H-fluorene

Chemical Property:

• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 288.09727168
• Heavy Atom Count: 21
• Complexity: 335

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1(C2=CC=CC=C2C3=CC=CC=C31)SC4=CC=CC=C4

Technology Process of 9-Methyl-9-phenylsulfanyl-9H-fluorene

There total 4 articles about 9-Methyl-9-phenylsulfanyl-9H-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9,9'-dimethyl-9,9'-bifluorene (15300-82-0) + thiophenol (108-98-5) → 9-methylfluorene (2523-37-7) + 9-methyl-9-fluorenyl phenyl thioether (102001-98-9)

Guidance literature:

In 1,3,5-trimethyl-benzene; at 99.8 ℃; Kinetics; Thermodynamic data; ΔG(excit.), ΔH(excit.), ΔS(excit.); other temperatures;

Reference yield:

9H-fluoren-9-yl bromide (1940-57-4) → 9-methyl-9-fluorenyl phenyl thioether (102001-98-9)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOMe / methanol

2: MeLi / diethyl ether

With methyllithium; sodium methylate; In methanol; diethyl ether;

DOI:10.1139/v60-129

Reference yield:

thiophenol (108-98-5) → 9-methyl-9-fluorenyl phenyl thioether (102001-98-9)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOMe / methanol

2: MeLi / diethyl ether

With methyllithium; sodium methylate; In methanol; diethyl ether;

DOI:10.1139/v60-129

upstream raw materials:

9,9'-dimethyl-9,9'-bifluorene

thiophenol

(9H-fluoren-9-yl) (phenyl) sulfane

methyl iodide

Downstream raw materials:

Phenyl-<9-methyl-fluorenyl-(9)>-sulfon