(C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅)

Base Information

• Chemical Name: (C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅)
• CAS No.: 64494-48-0
• Molecular Formula: C₃₂H₂₉FeO₂P
• Molecular Weight: 532.402
• Mol file: 64494-48-0.mol

Synonyms:(C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅)

Chemical Property of (C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅)

There total 3 articles about (C₅H₅)(CO)((C₆H₅)3P)FeCH(OCH₃)(C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(η(5)-C5H5)(CO)2Fe-CH(OMe)Ph (64494-50-4) → (C5H5)(CO)((C6H5)3P)FeCH(OCH3)(C6H5) (64494-48-0)

Guidance literature:

With triphenylphosphine; In benzene; Irradiation (UV/VIS); soln. stirred under N2 and irradiated (450W quartz filtered mercury vapor lamp, 2h), color changed from yellow to deep red); filtered (Celite); concn. (brown oil); dissolved in CH2Cl2/heptane, slowly evapn. gave a solid;

DOI:10.1021/om00103a016

Reference yield:

(C5H5)(CO)(P(C6H5)3)FeCHC6H5(1+)*CF3COO(1-)=(C5H5)(CO)(P(C6H5)3)FeCHC6H5O2CCF3 + sodium methoxide-d3 (6552-73-4) → (C5H5)(CO)((C6H5)3P)FeCH(OCH3)(C6H5) (64494-48-0)

Guidance literature:

In d⁽⁴⁾-methanol; dichloromethane-d2; A soln. of Fe complex in CD2Cl2 is added dropwise to a CD3OD/CD3ONa soln. cooled to 0°C, which is purged with N2.; Soln. is immediately cooled to -78°C, sealed under vacuum, and maintained at this temp., until a (1)H-NMR spectrum at -42°C is recorded.; Kinetics;

DOI:10.1021/ja00184a025

Reference yield:

sodium tetrahydroborate (16940-66-2) + (C5H5)(CO)(P(C6H5)3)FeC(OCH3)C6H5(1+)*CF3SO3(1-)=(C5H5)(CO)(P(C6H5)3)FeC(OCH3)C6H5O3SCF3 (117094-55-0) + sodium methoxide-d3 (6552-73-4) → (C5H5)(CO)((C6H5)3P)FeCH(OCH3)(C6H5) (64494-48-0)

Guidance literature:

In d⁽⁴⁾-methanol; dichloromethane-d2; A soln. of Fe complex in CD2Cl2 is added dropwise to a CD3OD/CD3ONa/NaBH4 soln. cooled to 0 or -78°C, which is purged with N2.; Sample is cooled to -78°C, sealed under vacuum, and maintained at this temp. until NMR spectrum at -42°C is recorded.;

DOI:10.1021/ja00184a025

upstream raw materials:

sodium tetrahydroborate

(C₅H₅)(CO)(P(C₆H₅)3)FeC(OCH₃)C₆H₅⁽¹⁺⁾*CF₃SO₃^(1-)=(C₅H₅)(CO)(P(C₆H₅)3)FeC(OCH₃)C₆H₅O₃SCF₃

sodium methoxide-d3

(η(5)-C5H5)(CO)2Fe-CH(OMe)Ph

Downstream raw materials:

[(η5-C5H5)Fe(NO)(P(C6H5)3)(CHC6H5)]PF6

Cp(CO)(PPh₃)Fe=CH(C₆H₅)AsF₆

Refernces