Ru₄H₃(CO)10C₆H₅PCH₂P(C₆H₅)2

Base Information

• Chemical Name: Ru₄H₃(CO)10C₆H₅PCH₂P(C₆H₅)2
• CAS No.: 98976-61-5
• Molecular Formula: C₂₉H₂₀O₁₀P₂Ru₄
• Molecular Weight: 994.699
• Mol file: 98976-61-5.mol

Synonyms:Ru₄H₃(CO)10C₆H₅PCH₂P(C₆H₅)2

Chemical Property of Ru₄H₃(CO)10C₆H₅PCH₂P(C₆H₅)2

Chemical Property:

Purity/Quality:

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Technology Process of Ru₄H₃(CO)10C₆H₅PCH₂P(C₆H₅)2

There total 2 articles about Ru₄H₃(CO)10C₆H₅PCH₂P(C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

Ru4H4*10CO*(C6H5)4P2CH2=Ru4H4(CO)10(C6H5)4P2CH2 (98976-60-4) → Ru4H3(CO)10C6H5PCH2P(C6H5)2 (98976-61-5)

Guidance literature:

In toluene; toluene soln. of complex was heated at 95°C for 4 h (N2); chromy. on silica gel, eluent toluene-hexane, recrystd. from CH2Cl2-hexane; elem. anal.;

Reference yield: 49.7%

Ru4H4*10CO*(C6H5)4P2CH2=Ru4H4(CO)10(C6H5)4P2CH2 (98976-60-4) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + Ru3(μ-H)(CO)9(μ3-PPhCH2PPh2) + Ru4H3(CO)10C6H5PCH2P(C6H5)2 (98976-61-5)

Guidance literature:

With CO; In toluene; CO was bubbled through a toluene soln. of complex heated under reflux for 3 h, the soln. was cooled;; chromy. on silica gel column, eluent heptane-toluene;;

Reference yield: 80.5%

Ru4H3(CO)10C6H5PCH2P(C6H5)2 (98976-61-5) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + Ru3(μ-H)(CO)9(μ3-PPhCH2PPh2)

Guidance literature:

With CO; In toluene; CO was bubbled through a toluene soln. of complex heated under reflux for 3 h, the soln. was cooled; chromy. on silica gel, eluent heptane-toluene;

upstream raw materials:

Ru₄H₄*10CO*(C₆H₅)4P₂CH₂=Ru₄H₄(CO)10(C₆H₅)4P₂CH₂

Downstream raw materials:

dodecacarbonyl-triangulo-triruthenium

Refernces