phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

Base Information

Chemical Name:phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside
CAS No.:922183-02-6
Molecular Formula:C₃₁H₃₅O₈PS
Molecular Weight:598.654
Hs Code.:

Synonyms:phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

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Chemical Property of phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

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Technology Process of phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

There total 1 articles about phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 922183-02-6
phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / phosphorus oxychloride; triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

2: 88 percent / NaH / various solvent(s); tetrahydrofuran / 13 h / 20 °C

With sodium hydride; triethylamine; trichlorophosphate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200602699

Reference yield: 88.0%

: 922183-02-6
phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

: 922183-06-0
C₃₁H₃₇O₈PS

Guidance literature:: phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside; With triethylsilane; 4 A molecular sieve; phenylborondichloride; In dichloromethane; at -78 ℃; for 0.5h;

With sodium hydrogencarbonate; In water; Further stages.;
DOI:10.1002/anie.200602699

Reference yield:

: 922183-02-6
phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-(2,2-dimethyltrimethylene-phosphonoyl)-β-D-thioglucopyranoside

: 922183-14-0
C₆₃H₇₄O₁₆P₂S

Guidance literature:: Multi-step reaction with 2 steps

1.1: molecular sieves 4 Angstroem; PhBCl₂; Et₃SiH / CH₂Cl₂ / 0.5 h / -78 °C

1.2: 88 percent / NaHCO₃ / H₂O

2.1: benzenesulfenylpiperidine; 2,6-di-tert-butyl-4-methylpyridine; Tf₂O / CH₂Cl₂ / -60 °C

2.2: 100 percent / CH₂Cl₂ / -60 °C

With triethylsilane; 2,6-di-tert-butyl-4-methylpyridine; 1-(phenylsulphenyl)piperidylamide; trifluoromethylsulfonic anhydride; 4 A molecular sieve; phenylborondichloride; In dichloromethane;
DOI:10.1002/anie.200602699