1-(4-methylphenyl)-2-ferrocenylacetylene

Base Information

Chemical Name:1-(4-methylphenyl)-2-ferrocenylacetylene
CAS No.:72022-41-4
Molecular Formula:C₁₉H₁₆Fe
Molecular Weight:300.183
Hs Code.:

Synonyms:1-(4-methylphenyl)-2-ferrocenylacetylene

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Chemical Property of 1-(4-methylphenyl)-2-ferrocenylacetylene

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Technology Process of 1-(4-methylphenyl)-2-ferrocenylacetylene

There total 4 articles about 1-(4-methylphenyl)-2-ferrocenylacetylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1271-47-2
ferroceneacetylene

: 67254-06-2,53424-02-5
trans-PtI(PPh₃)2C₆H₄Me-p

: 72022-41-4
1-(4-methylphenyl)-2-ferrocenylacetylene

Guidance literature:: With Et₂NH; copper(l) iodide; In dichloromethane; N2-atmosphere; stirring (room temp., 20 min); evapn., chromy. (alumina, CH2Cl2 / hexane); elem. anal.;

Reference yield: 65.3%

: 1271-47-2
ferroceneacetylene

: 624-31-7
4-tolyl iodide

: 72022-41-4
1-(4-methylphenyl)-2-ferrocenylacetylene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; at 80 ℃; for 2h; Reflux; Inert atmosphere;
DOI:10.1039/C6DT04339A

Reference yield: 42.0%

: 1-ethynylferrocene

: 2749-93-1
1-methyl-4-(1-propyn-1-yl)benzene

: 72022-41-4
1-(4-methylphenyl)-2-ferrocenylacetylene

Guidance literature:: With Mo(CO)6; FC₆H₄OH; In toluene; byproducts: diferrocenylethyne, CH3C6H4CCC6H4CH3; (Ar); addn. of molybdenum compd., phenol deriv. and propynyl deriv. to soln. of ferrocene deriv. in dry toluene, heating at 120-130°C for3 h, TLC monitoring; treatment with 1 M NaOH, extn. (CH2Cl2), washing organic phase with water and brine, drying over MgSO4, evapn., chromy. (silica gel, hexane/CHCl3(5:1)), elem. anal.;
DOI:10.1002/ejic.200800128