4-Acetoxy-3-methoxycinnamaldehyde

Base Information

Chemical Name:4-Acetoxy-3-methoxycinnamaldehyde
CAS No.:83071-67-4
Molecular Formula:C₁₂H₁₂O₄
Molecular Weight:220.225
Hs Code.:
European Community (EC) Number:265-733-2,625-929-4
Nikkaji Number:J307.390D
Wikidata:Q27159260
Metabolomics Workbench ID:70705
Mol file:83071-67-4.mol

Synonyms:4-acetoxy-3-methoxycinnamaldehyde;83071-67-4;65401-83-4;4-Acetoxy-3-methoxycinnamaldehyde, predominantly trans;[2-methoxy-4-[(E)-3-oxoprop-1-enyl]phenyl] acetate;4-(2-Formylvinyl)-2-methoxyphenyl acetate;EINECS 265-733-2;bmse010073;4-acetoxy-3-methoxy-trans-cinnamaldehyde;(e)-2-methoxy-4-(3-oxoprop-1-enyl)phenyl acetate;AC1NYVJK;AC1Q46BZ;ST055640;SCHEMBL3241263;2-Propenal,3-[4-(acetyloxy)-3-methoxyphenyl]-,(2E)-;CHEBI:86579;VEKAJHBFBMWJKI-ONEGZZNKSA-N;AKOS024282339;3-(3-Methoxy-4-acetoxyphenyl)propenal;AM85923;2-Propenal, 3-[4-(acetyloxy)-3-methoxyphenyl]-;2-methoxy-4-(3-oxoprop-1-en-1-yl)phenyl acetate;Q27159260;(E)-2-methoxy-4-(3-oxoprop-1-en-1-yl)phenyl acetate;2-methoxy-4-[(1E)-3-oxoprop-1-en-1-yl]phenyl acetate;4-Acetoxy-3-methoxycinnamaldehyde, predominantly trans, 95%

Suppliers and Price of 4-Acetoxy-3-methoxycinnamaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Acetoxy-3-methoxycinnamaldehyde
50mg
$ 45.00

Sigma-Aldrich
4-Acetoxy-3-methoxycinnamaldehyde, predominantly trans 95%
5g
$ 103.00

Total 6 raw suppliers

Chemical Property of 4-Acetoxy-3-methoxycinnamaldehyde

Chemical Property:

Melting Point:97-100oC(lit.)
Boiling Point:342.7±27.0 °C(Predicted)
PSA：52.60000
Density:>0 (vs air)
LogP:1.83260
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:220.07355886
Heavy Atom Count:16
Complexity:272

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Acetoxy-3-methoxycinnamaldehyde ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OC1=C(C=C(C=C1)C=CC=O)OC
Isomeric SMILES:CC(=O)OC1=C(C=C(C=C1)/C=C/C=O)OC

Technology Process of 4-Acetoxy-3-methoxycinnamaldehyde

There total 12 articles about 4-Acetoxy-3-methoxycinnamaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1006614-61-4
2-methoxy-4-(3-oxopropyl)phenyl ethanoate

: 65401-83-4,83071-67-4
(E)-2-methoxy-4-(3-oxoprop-1-en-1-yl)phenyl acetate

Guidance literature:: With (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dichloromethane; at 20 ℃; for 5h; stereoselective reaction;
DOI:10.1007/s11426-011-4432-6

Reference yield: 76.0%

: 93-28-7
eugenol acetate

: 65401-83-4,83071-67-4
(E)-2-methoxy-4-(3-oxoprop-1-en-1-yl)phenyl acetate

Guidance literature:: With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,2-dichloro-ethane; at 50 ℃; for 3h;
DOI:10.1055/s-0037-1609554

Reference yield: 58.0%

: 69017-41-0
(E)-3-(4-acetoxy-3-methoxyphenyl)-2-propen-1-ol

: 65401-83-4,83071-67-4
(E)-2-methoxy-4-(3-oxoprop-1-en-1-yl)phenyl acetate

Guidance literature:: With iodine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; In acetonitrile; at 20 ℃; for 0.25h; Molecular sieve; Inert atmosphere;
DOI:10.3762/bjoc.12.51