[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

Base Information

Chemical Name:[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel
CAS No.:869954-98-3
Molecular Formula:C₃₄H₄₄N₂NiO
Molecular Weight:555.426
Hs Code.:

Synonyms:[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

Suppliers and Price of [N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

There total 2 articles about [N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: potassium N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidate

: 100-44-7
benzyl chloride

: 869954-98-3
[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

Guidance literature:: With 2,3-Dimethylaniline; In tetrahydrofuran; (Ar); Schlenk technique; exclusion of light; soln. of Ni complex/THF wastreated with K salt of ligand in THF and Me2NC6H5 at -35°C; soln . of benzyl chloride in THF was added at -35°C; mixt. was warmed to room temp. and stirred overnight; volatiles removed (vac.); extd. (pentane); filtered; concd.; crystd. at -35°C overnight; crystd. (pentane); elem. anal.;
DOI:10.1021/om050640g

Reference yield:

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 585-48-8
2,6-di-tert-butyl-pyridine

: potassium N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidate

: 100-44-7
benzyl chloride

: 869954-98-3
[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

: [N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,O](η1-benzyl)nickel(2,6-di(tert-butyl)pyridine)

Guidance literature:: In tetrahydrofuran; (inert atm., dark); treatment of nickel compd. with benzyl chloride and pyridine deriv. in THF in presence of potassium salt at room temp. for 12 h;
DOI:10.1021/om070155g

Reference yield: 95.0%

: 110-86-1
pyridine

: 869954-98-3
[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η3-benzyl)nickel

: 957473-12-0,950837-31-7,957319-60-7,952319-44-7
[N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamidato-κ2N,N](η1-benzyl)nickel(pyridine)

Guidance literature:: In toluene; (inert atm.); addn. of 4 equiv. of pyridine to soln. of nickel compd. intoluene, stirring for 1 h; evapn., extn. (ether-pentane (1:2)), keeping at room temp. overnight, isolation of crystals, NMR;
DOI:10.1021/om070155g