p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside
CAS No.:1363157-77-0
Molecular Formula:C₄₀H₅₀O₅SSi
Molecular Weight:670.986
Hs Code.:

Synonyms:p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

Suppliers and Price of p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

There total 1 articles about p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 479252-05-6
((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol

: 1363157-77-0
p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With pyridine; dmap; at 0 - 70 ℃; for 16h;
DOI:10.1021/ja300284x

Reference yield: 89.0%

: 1363157-77-0
p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

: 2-azidoethyl (2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-(1→3)-(2-O-benzoyl-6-Obenzyl-β-D-galactopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 2-azidoethyl (2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-(1→3)-[(2,3,4-tri-O-benzyl-6-Otert-butyldimethylsilyl-α-D-glucopyranosyl)-(1→4)]-(2-O-benzoyl-6-O-benzyl-β-D-glucopyranosyl)-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With p-methylbenzenesulfenyl chloride; silver trifluoromethanesulfonate; In diethyl ether; at -78 - 20 ℃; for 1.58333h; stereoselective reaction; Molecular sieve;
DOI:10.1021/acs.orglett.6b02796

Reference yield:

: 1261222-55-2
4-methylphenyl 2,3,6-tri-O-benzoyl-4-O-(2,3-di-O-benzoyl-6-O-benzyl-β-D-galactopyranosyl)-1-thio-β-D-glucopyranoside

: 1363157-77-0
p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside

: C₉₄H₉₆O₂₀SSi

Guidance literature:: p-methylphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldimethylsilyl-1-deoxy-1-thio-β-D-glucopyranoside; With silver trifluoromethanesulfonate; In diethyl ether; at -78 ℃; for 0.166667h; Molecular sieve;

With p-methylbenzenesulfenyl chloride; In diethyl ether; at -78 ℃; for 0.25h; Molecular sieve;

4-methylphenyl 2,3,6-tri-O-benzoyl-4-O-(2,3-di-O-benzoyl-6-O-benzyl-β-D-galactopyranosyl)-1-thio-β-D-glucopyranoside; In diethyl ether; dichloromethane; at -78 - 20 ℃; for 1.5h; stereoselective reaction; Molecular sieve;
DOI:10.1021/acs.orglett.9b00653