(2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate

Base Information

Chemical Name:(2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate
CAS No.:1083348-83-7
Molecular Formula:C₂₄H₃₈O₅Si
Molecular Weight:434.648
Hs Code.:

Synonyms:(2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate

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Technology Process of (2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate

There total 1 articles about (2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 994-30-9
triethylsilyl chloride

: 807363-99-1
methyl (2Z,5R)-5-hydroxy-6-(4-methoxybenzyloxy)-3-prop-2-enylhex-2-enoate

: 1083348-83-7
(2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1039/c7ob02127e

Reference yield: 76.0%

: 1083348-83-7
(2Z)-methyl 3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]hexa-2,5-dienoate

: 1083349-07-8
methyl (2Z,5RS)-3-[(2R)-3-(4-methoxybenzyloxy)-2-triethylsilyloxypropyl]-5,6-dihydroxyhex-2-enoate

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; tert-butyl alcohol; at 20 ℃; for 4h; regioselective reaction;
DOI:10.1016/j.tetlet.2008.08.075