(E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

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Chemical Name:(E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol
CAS No.:874301-10-7
Molecular Formula:C₃₄H₄₇IO₄Si
Molecular Weight:674.735
Hs Code.:

Synonyms:(E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

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Chemical Property of (E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

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Technology Process of (E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

There total 1 articles about (E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: (3E)-4-(tributylstannyl)-6-(tert-butyldiphenylsilyloxy)-1-((1S,2R,6R)-2-(methoxymethoxy)-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl)hex-3-en-2-ol

: 874301-10-7
(E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

Guidance literature:: With iodine; In dichloromethane; at -78 ℃; for 0.0833333h;
DOI:10.1021/jo0520691

Reference yield:

: (E)-ethyl 6-(4-methoxybenzyloxy)-3-(tributylstannyl)hex-2-enoate

: 874301-10-7
(E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

: 874301-15-2
(2E,4E)-ethyl 4-(2-[tert-butyldiphenylsilyloxy]ethyl)-3-(3-(4-methoxybenzyloxy)propyl)-7-((1S,2R,6R)-2-(methoxymethoxy)-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl)-6-oxohepta-2,4-dienoate

Guidance literature:: (E)-ethyl 6-(4-methoxybenzyloxy)-3-(tributylstannyl)hex-2-enoate; (E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) chloride; lithium chloride; In dimethyl sulfoxide; at 20 ℃; for 20h;

With tetrapropylammonium perruthennate; 4 A molecular sieve; 4-methylmorpholine N-oxide; In dichloromethane; acetonitrile; for 0.5h;
DOI:10.1021/jo0520691

Reference yield:

: (E)-ethyl 6-(4-methoxybenzyloxy)-3-(tributylstannyl)hex-2-enoate

: 874301-10-7
(E)-6-(tert-Butyl-diphenyl-silanyloxy)-4-iodo-1-((1S,2R,6R)-6-isopropenyl-2-methoxymethoxy-3-methyl-cyclohex-3-enyl)-hex-3-en-2-ol

: (2E,4E)-ethyl 4-(2-[tert-butyldiphenylsilyloxy]ethyl)-6-hydroxy-3-(3-(4-methoxybenzyloxy)propyl)-7-((1S,2R,6R)-2-(methoxymethoxy)-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl)hepta-2,4-dienoate

: (2E,4E)-ethyl 4-(2-[tert-butyldiphenylsilyloxy]ethyl)-6-hydroxy-3-(3-(4-methoxybenzyloxy)propyl)-7-((1S,2R,6R)-2-(methoxymethoxy)-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl)hepta-2,4-dienoate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) chloride; lithium chloride; In dimethyl sulfoxide; at 20 ℃; for 20h;
DOI:10.1021/jo0520691